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Statements

Subject Item
n2:RIV%2F67985858%3A_____%2F11%3A00363096%21RIV12-AV0-67985858
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Intrinsic data of N(2)O catalytic decomposition over a K-promoted Co-Mn-Al mixed oxide prepared by the thermal treatment of a layered double hydroxide was used for the design of a pilot reactor for the abatement of N(2)O emissions from the off-gases in HNO(3) production. A pseudo-homogeneous one-dimensional model of an ideal plug flow reactor under an isothermal regime (450 degrees C) was used for reactor design. A catalyst particle diameter of 3 mm is a compromise size because increasing the size of the catalyst particle leads to a decrease in the reaction rate because of an internal diffusion limitation, and particles with a smaller diameter cause a large pressure drop. A catalyst bed of 11.5 m(3) was estimated for the target N(2)O conversion of 90% upon the treatment of 30000 m(3)/h of exhaust gas (0.1 mol% N(2)O, 0.005 mol% NO, 0.9 mol% H(2)O, 5 mol% O(2)) at 450 degrees C and 130 kPa. Intrinsic data of N(2)O catalytic decomposition over a K-promoted Co-Mn-Al mixed oxide prepared by the thermal treatment of a layered double hydroxide was used for the design of a pilot reactor for the abatement of N(2)O emissions from the off-gases in HNO(3) production. A pseudo-homogeneous one-dimensional model of an ideal plug flow reactor under an isothermal regime (450 degrees C) was used for reactor design. A catalyst particle diameter of 3 mm is a compromise size because increasing the size of the catalyst particle leads to a decrease in the reaction rate because of an internal diffusion limitation, and particles with a smaller diameter cause a large pressure drop. A catalyst bed of 11.5 m(3) was estimated for the target N(2)O conversion of 90% upon the treatment of 30000 m(3)/h of exhaust gas (0.1 mol% N(2)O, 0.005 mol% NO, 0.9 mol% H(2)O, 5 mol% O(2)) at 450 degrees C and 130 kPa.
dcterms:title
Simulation of N(2)O Abatement in Waste Gases by Its Decomposition over a K-Promoted Co-Mn-Al Mixed Oxide Catalyst Simulation of N(2)O Abatement in Waste Gases by Its Decomposition over a K-Promoted Co-Mn-Al Mixed Oxide Catalyst
skos:prefLabel
Simulation of N(2)O Abatement in Waste Gases by Its Decomposition over a K-Promoted Co-Mn-Al Mixed Oxide Catalyst Simulation of N(2)O Abatement in Waste Gases by Its Decomposition over a K-Promoted Co-Mn-Al Mixed Oxide Catalyst
skos:notation
RIV/67985858:_____/11:00363096!RIV12-AV0-67985858
n11:predkladatel
n12:ico%3A67985858
n3:aktivita
n13:P n13:Z
n3:aktivity
P(GA106/09/1664), Z(AV0Z40720504)
n3:cisloPeriodika
5/SI/
n3:dodaniDat
n20:2012
n3:domaciTvurceVysledku
n7:8799938
n3:druhVysledku
n10:J
n3:duvernostUdaju
n4:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
229459
n3:idVysledku
RIV/67985858:_____/11:00363096
n3:jazykVysledku
n18:eng
n3:klicovaSlova
nitrous oxide; catalytic decomposition; nitric acid production
n3:klicoveSlovo
n16:nitric%20acid%20production n16:nitrous%20oxide n16:catalytic%20decomposition
n3:kodStatuVydavatele
CN - Čínská lidová republika
n3:kontrolniKodProRIV
[9EFF767CCB3D]
n3:nazevZdroje
Chinese Journal of Catalysis
n3:obor
n17:CI
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n8:GA106%2F09%2F1664
n3:rokUplatneniVysledku
n20:2011
n3:svazekPeriodika
32
n3:tvurceVysledku
Karásková, K. Kovanda, F. Jirátová, Květa Obalová, L.
n3:wos
000291508200018
n3:zamer
n19:AV0Z40720504
s:issn
0253-9837
s:numberOfPages
5
n5:doi
10.1016/S1872-2067(10)60201-X