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Statements

Subject Item
n2:RIV%2F67985858%3A_____%2F09%3A00356436%21RIV11-AV0-67985858
rdf:type
skos:Concept n17:Vysledek
dcterms:description
Evaluation of micropore volume and mesopore surface area in microporous-mesoporous samples is presented. A series of mechanical mixtures of microporous zeolite NaY, and mesoporous gama-alumina was used for verification of the applicability of the (three-parameter) modified BET equation. The nitrogen adsorption isotherms (77 K) were analyzed by the modified (three parameters) BET equation and compared with the independent textural information obtained a) from t-plots (with the standard isotherm of nonporous gama-alumina and the standard isotherms of Lecloux-Pirard) and b) by subtracting the isotherm of the parent NaY from mixed sample isotherms. Similarly, nitrogen adsorption isotherms of rutile samples with micropores blocked by n-nonane, from the literature were tested. For illustration, the failure of classic (two-parameter) BET equation for microporous-mesoporous samples is demonstrated Evaluation of micropore volume and mesopore surface area in microporous-mesoporous samples is presented. A series of mechanical mixtures of microporous zeolite NaY, and mesoporous gama-alumina was used for verification of the applicability of the (three-parameter) modified BET equation. The nitrogen adsorption isotherms (77 K) were analyzed by the modified (three parameters) BET equation and compared with the independent textural information obtained a) from t-plots (with the standard isotherm of nonporous gama-alumina and the standard isotherms of Lecloux-Pirard) and b) by subtracting the isotherm of the parent NaY from mixed sample isotherms. Similarly, nitrogen adsorption isotherms of rutile samples with micropores blocked by n-nonane, from the literature were tested. For illustration, the failure of classic (two-parameter) BET equation for microporous-mesoporous samples is demonstrated
dcterms:title
Modified BET Equation for Determination of Micropore Pore Volume and Mesopore Surface Area in Microporous-Mesoporous Solids Modified BET Equation for Determination of Micropore Pore Volume and Mesopore Surface Area in Microporous-Mesoporous Solids
skos:prefLabel
Modified BET Equation for Determination of Micropore Pore Volume and Mesopore Surface Area in Microporous-Mesoporous Solids Modified BET Equation for Determination of Micropore Pore Volume and Mesopore Surface Area in Microporous-Mesoporous Solids
skos:notation
RIV/67985858:_____/09:00356436!RIV11-AV0-67985858
n3:aktivita
n14:Z n14:P
n3:aktivity
P(IAA4072404), P(KAN400720701), Z(AV0Z40720504)
n3:dodaniDat
n15:2011
n3:domaciTvurceVysledku
n12:5916887 n12:2983141 n12:9345531
n3:druhVysledku
n21:D
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
327124
n3:idVysledku
RIV/67985858:_____/09:00356436
n3:jazykVysledku
n20:eng
n3:klicovaSlova
microporous-mesoporous solids; mesopore surface area; BET equation
n3:klicoveSlovo
n4:microporous-mesoporous%20solids n4:BET%20equation n4:mesopore%20surface%20area
n3:kontrolniKodProRIV
[90250F9CC522]
n3:mistoKonaniAkce
Edinburg
n3:mistoVydani
Cambridge
n3:nazevZdroje
Characterisation of Porous Solids VIII
n3:obor
n9:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
4
n3:projekt
n8:KAN400720701 n8:IAA4072404
n3:rokUplatneniVysledku
n15:2009
n3:tvurceVysledku
Matějová, Lenka Šolcová, Olga Schneider, Petr Hudec, P.
n3:typAkce
n18:WRD
n3:wos
000269656900029
n3:zahajeniAkce
2008-06-10+02:00
n3:zamer
n7:AV0Z40720504
s:numberOfPages
7
n16:hasPublisher
Royal Society of Chemistry Publishing
n19:isbn
978-1-84755-904-3