This HTML5 document contains 40 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n10http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n5http://linked.opendata.cz/resource/domain/vavai/projekt/
n16http://linked.opendata.cz/ontology/domain/vavai/
n13http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n15http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F67985858%3A_____%2F09%3A00332318%21RIV10-AV0-67985858/
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n12http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n18http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n11http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n7http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n17http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n14http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n9http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F67985858%3A_____%2F09%3A00332318%21RIV10-AV0-67985858
rdf:type
skos:Concept n16:Vysledek
dcterms:description
The multicenter bond indices, recently proposed as quantitative measures of the cyclic delocalization in aromatic systems, have been applied to characterize the differences in the nature of the electron reorganization in a series of allowed and forbidden electrocyclic reactions of linear neutral polyenes of general formula CnHn+2 and related charged systems of formula CnHn+2(+) and CnHn+2(-) for n ranging from 4 to 7. The proposed methodology, which is based on the monitoring of the variation of the extent of cyclic delocalization along the concerted reaction paths, is shown to be completely consistent with the empirical Evans/Dewar classification anticipating aromatic transition states for allowed and antiaromatic transition states for forbidden electrocyclic reactions. The multicenter bond indices, recently proposed as quantitative measures of the cyclic delocalization in aromatic systems, have been applied to characterize the differences in the nature of the electron reorganization in a series of allowed and forbidden electrocyclic reactions of linear neutral polyenes of general formula CnHn+2 and related charged systems of formula CnHn+2(+) and CnHn+2(-) for n ranging from 4 to 7. The proposed methodology, which is based on the monitoring of the variation of the extent of cyclic delocalization along the concerted reaction paths, is shown to be completely consistent with the empirical Evans/Dewar classification anticipating aromatic transition states for allowed and antiaromatic transition states for forbidden electrocyclic reactions.
dcterms:title
Electron Reorganization in Allowed and Forbidden Reactions: Multicenter Bond Indices as a Measure of Aromaticity and/or Anti-aromaticity in Transition States of Pericyclic Electrocyclizations Electron Reorganization in Allowed and Forbidden Reactions: Multicenter Bond Indices as a Measure of Aromaticity and/or Anti-aromaticity in Transition States of Pericyclic Electrocyclizations
skos:prefLabel
Electron Reorganization in Allowed and Forbidden Reactions: Multicenter Bond Indices as a Measure of Aromaticity and/or Anti-aromaticity in Transition States of Pericyclic Electrocyclizations Electron Reorganization in Allowed and Forbidden Reactions: Multicenter Bond Indices as a Measure of Aromaticity and/or Anti-aromaticity in Transition States of Pericyclic Electrocyclizations
skos:notation
RIV/67985858:_____/09:00332318!RIV10-AV0-67985858
n3:aktivita
n7:Z n7:P
n3:aktivity
P(GA203/09/0118), Z(AV0Z40720504)
n3:cisloPeriodika
12
n3:dodaniDat
n9:2010
n3:domaciTvurceVysledku
n10:9028404
n3:druhVysledku
n14:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
312860
n3:idVysledku
RIV/67985858:_____/09:00332318
n3:jazykVysledku
n11:eng
n3:klicovaSlova
pericycli reactions; aromaticity; multicenter bond indices
n3:klicoveSlovo
n12:multicenter%20bond%20indices n12:aromaticity n12:pericycli%20reactions
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[C0E272ADFC76]
n3:nazevZdroje
Journal of Physical Organic Chemistry
n3:obor
n17:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:projekt
n5:GA203%2F09%2F0118
n3:rokUplatneniVysledku
n9:2009
n3:svazekPeriodika
22
n3:tvurceVysledku
Mandado, M. Ponec, Robert
n3:wos
000272727700013
n3:zamer
n13:AV0Z40720504
s:issn
0894-3230
s:numberOfPages
8