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Statements

Subject Item
n2:RIV%2F67985858%3A_____%2F06%3A00081859%21RIV07-AV0-67985858
rdf:type
n16:Vysledek skos:Concept
dcterms:description
Vapour-liquid equilibrium accompanied with chemical reaction in the quaternary water + methanol + acetic acid + methyl acetate system was measured in a circulation still; 20 experimental points at 323.15 K were determined. For the complete and consistent description, the isothermal VLE data in the four non-reacting binary subsystems were measured, too. The data were correlated by means of the maximum likelihood procedure by using the NRTL model; binary model parameters for the binary subsystems were obtained from experimental vapour–liquid equilibrium data by using either the Hayden–O'Connell or Marek–Standart correction as appropriate, to account for the non-ideality of vapour phase. NRTL parameters for the reacting binary subsystems were estimated from the global optimization based on the quaternary experimental data. By using transformed composition variables, two–dimensional phase diagrams for the quaternary system have been constructed. Fázová rovnováha spojená s chemickou reakcí byla stanovena ve čtyřsložkové soustavě voda + methanol + kyselina octová + methylacetát. Pro úplný termodynamický popis byly změřeny 4 nereaktivní binární subsystémy. Data byla korelována metodou maximální věrohodnosti s použitím NRTL modelu uvažujíce korekce na asociaci v plynné fázi (Marek-Standart). Parametry NRTL pro reaktivní bináry byly stanoveny globální optimalizací quaternárních dat. Dvourozměrné digramy byly zkonstruovány s pomocí transformace koncentračních proměnných. Vapour-liquid equilibrium accompanied with chemical reaction in the quaternary water + methanol + acetic acid + methyl acetate system was measured in a circulation still; 20 experimental points at 323.15 K were determined. For the complete and consistent description, the isothermal VLE data in the four non-reacting binary subsystems were measured, too. The data were correlated by means of the maximum likelihood procedure by using the NRTL model; binary model parameters for the binary subsystems were obtained from experimental vapour–liquid equilibrium data by using either the Hayden–O'Connell or Marek–Standart correction as appropriate, to account for the non-ideality of vapour phase. NRTL parameters for the reacting binary subsystems were estimated from the global optimization based on the quaternary experimental data. By using transformed composition variables, two–dimensional phase diagrams for the quaternary system have been constructed.
dcterms:title
Isothermal Vapour-Liquid Equilibrium with Chemical Reaction in the Quaternary Water + Methanol + Acetic Acid + Methyl Acetate System, and in Five Binary Subsystems. Izotermní rovnováha kapalina-pára s chemickou reakcí ve čtyřsložkové soustavě voda + methanol + kyselina octová + methylacetát, a v pěti binárních subsystémech. Isothermal Vapour-Liquid Equilibrium with Chemical Reaction in the Quaternary Water + Methanol + Acetic Acid + Methyl Acetate System, and in Five Binary Subsystems.
skos:prefLabel
Isothermal Vapour-Liquid Equilibrium with Chemical Reaction in the Quaternary Water + Methanol + Acetic Acid + Methyl Acetate System, and in Five Binary Subsystems. Isothermal Vapour-Liquid Equilibrium with Chemical Reaction in the Quaternary Water + Methanol + Acetic Acid + Methyl Acetate System, and in Five Binary Subsystems. Izotermní rovnováha kapalina-pára s chemickou reakcí ve čtyřsložkové soustavě voda + methanol + kyselina octová + methylacetát, a v pěti binárních subsystémech.
skos:notation
RIV/67985858:_____/06:00081859!RIV07-AV0-67985858
n4:strany
96;101
n4:aktivita
n12:Z n12:P
n4:aktivity
P(GA203/03/1588), Z(AV0Z40720504)
n4:cisloPeriodika
1-2
n4:dodaniDat
n8:2007
n4:domaciTvurceVysledku
n7:3728145 n7:6816363 n7:9504133
n4:druhVysledku
n17:J
n4:duvernostUdaju
n14:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
480529
n4:idVysledku
RIV/67985858:_____/06:00081859
n4:jazykVysledku
n9:eng
n4:klicovaSlova
esterification; chemical equilibria; phase equilibria
n4:klicoveSlovo
n13:esterification n13:phase%20equilibria n13:chemical%20equilibria
n4:kodStatuVydavatele
NL - Nizozemsko
n4:kontrolniKodProRIV
[0D84FA278244]
n4:nazevZdroje
Fluid Phase Equilibria
n4:obor
n18:CF
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
3
n4:projekt
n5:GA203%2F03%2F1588
n4:rokUplatneniVysledku
n8:2006
n4:svazekPeriodika
247
n4:tvurceVysledku
Wichterle, Ivan Bernatová, Svatoslava Aim, Karel
n4:zamer
n10:AV0Z40720504
s:issn
0378-3812
s:numberOfPages
6