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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F13%3A33147800%21RIV14-GA0-15310___
rdf:type
n13:Vysledek skos:Concept
rdfs:seeAlso
http://pubs.acs.org/doi/ipdf/10.1021/nn4024027
dcterms:description
Graphene derivatives containing covalently bound halogens (graphene halides) represent promising two-dimensional systems having interesting physical and chemical properties. The attachment of halogen atoms to sp(2) carbons changes the hybridization state to sp(3), which has a principal impact on electronic properties and local structure of the material. The fully fluorinated graphene derivative, fluorographene (graphene fluoride, C1F1), is the thinnest insulator and the only stable stoichiometric graphene halide (C1X1). In this review, we discuss structural properties, syntheses, chemistry, stabilities, and electronic properties of fluorographene and other partially fluorinated, chlorinated, and brominated graphenes. Remarkable optical, mechanical, vibrational, thermodynamic, and conductivity properties of graphene halides are also explored as well as the properties of rare structures including multilayered fluorinated graphenes, iodine-doped graphene, and mixed graphene halides. Finally, patterned halogenation is presented as an interesting approach for generating materials with applications in the field of graphene-based electronic devices. Graphene derivatives containing covalently bound halogens (graphene halides) represent promising two-dimensional systems having interesting physical and chemical properties. The attachment of halogen atoms to sp(2) carbons changes the hybridization state to sp(3), which has a principal impact on electronic properties and local structure of the material. The fully fluorinated graphene derivative, fluorographene (graphene fluoride, C1F1), is the thinnest insulator and the only stable stoichiometric graphene halide (C1X1). In this review, we discuss structural properties, syntheses, chemistry, stabilities, and electronic properties of fluorographene and other partially fluorinated, chlorinated, and brominated graphenes. Remarkable optical, mechanical, vibrational, thermodynamic, and conductivity properties of graphene halides are also explored as well as the properties of rare structures including multilayered fluorinated graphenes, iodine-doped graphene, and mixed graphene halides. Finally, patterned halogenation is presented as an interesting approach for generating materials with applications in the field of graphene-based electronic devices.
dcterms:title
Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives
skos:prefLabel
Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives Halogenated Graphenes: Rapidly Growing Family of Graphene Derivatives
skos:notation
RIV/61989592:15310/13:33147800!RIV14-GA0-15310___
n13:predkladatel
n14:orjk%3A15310
n3:aktivita
n18:P
n3:aktivity
P(ED2.1.00/03.0058), P(EE2.3.20.0017), P(EE2.3.30.0041), P(GBP208/12/G016)
n3:cisloPeriodika
8
n3:dodaniDat
n10:2014
n3:domaciTvurceVysledku
n11:3151948 n11:9251189 n11:5772133 Kasibhatta, Kumara Ramanatha Datta
n3:druhVysledku
n20:J
n3:duvernostUdaju
n4:S
n3:entitaPredkladatele
n21:predkladatel
n3:idSjednocenehoVysledku
77013
n3:idVysledku
RIV/61989592:15310/13:33147800
n3:jazykVysledku
n12:eng
n3:klicovaSlova
1ST-PRINCIPLES; GRAPHANE; OXIDE; FUNCTIONALIZATION; FLUOROGRAPHENE; MOLECULAR-DYNAMICS; GRAPHITE FLUORIDE; MAGNETIC-PROPERTIES; SURFACE-FLUORINATED GRAPHENE; INFRARED SPECTRAL SIGNATURES
n3:klicoveSlovo
n6:SURFACE-FLUORINATED%20GRAPHENE n6:FUNCTIONALIZATION n6:FLUOROGRAPHENE n6:INFRARED%20SPECTRAL%20SIGNATURES n6:OXIDE n6:1ST-PRINCIPLES n6:GRAPHANE n6:GRAPHITE%20FLUORIDE n6:MOLECULAR-DYNAMICS n6:MAGNETIC-PROPERTIES
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[58F4870D02B8]
n3:nazevZdroje
ACS Nano
n3:obor
n16:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n9:EE2.3.30.0041 n9:GBP208%2F12%2FG016 n9:ED2.1.00%2F03.0058 n9:EE2.3.20.0017
n3:rokUplatneniVysledku
n10:2013
n3:svazekPeriodika
7
n3:tvurceVysledku
Karlický, František Otyepka, Michal Zbořil, Radek Kasibhatta, Kumara Ramanatha Datta
n3:wos
000323810600004
s:issn
1936-0851
s:numberOfPages
31
n17:doi
10.1021/nn4024027
n19:organizacniJednotka
15310