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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F13%3A33147718%21RIV15-MSM-15310___
rdf:type
skos:Concept n16:Vysledek
dcterms:description
Macrocycles were synthesised via the cyclisation of propargyl 2-azidobenzoate using 'click' chemistry. An LC/MS-based method for the separation of macrocycles is described. In the present work, the influence of various catalysts and reaction conditions on the course of the reaction is evaluated. The reaction is very sensitive to the conditions, and it is demonstrated that it is possible to modify the ratio of macrocycles by varying the reaction conditions. The cyclisation of propargyl 2-azidobenzoate represents an economical method for the preparation of the studied macrocycles Macrocycles were synthesised via the cyclisation of propargyl 2-azidobenzoate using 'click' chemistry. An LC/MS-based method for the separation of macrocycles is described. In the present work, the influence of various catalysts and reaction conditions on the course of the reaction is evaluated. The reaction is very sensitive to the conditions, and it is demonstrated that it is possible to modify the ratio of macrocycles by varying the reaction conditions. The cyclisation of propargyl 2-azidobenzoate represents an economical method for the preparation of the studied macrocycles
dcterms:title
Study of direct macrocycle formation via the cyclisation of propargyl 2-azidobenzoate Study of direct macrocycle formation via the cyclisation of propargyl 2-azidobenzoate
skos:prefLabel
Study of direct macrocycle formation via the cyclisation of propargyl 2-azidobenzoate Study of direct macrocycle formation via the cyclisation of propargyl 2-azidobenzoate
skos:notation
RIV/61989592:15310/13:33147718!RIV15-MSM-15310___
n3:aktivita
n12:P n12:Z
n3:aktivity
P(ME09057), Z(MSM6198959216)
n3:cisloPeriodika
10
n3:dodaniDat
n5:2015
n3:domaciTvurceVysledku
n18:8225583
n3:druhVysledku
n10:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
108674
n3:idVysledku
RIV/61989592:15310/13:33147718
n3:jazykVysledku
n19:eng
n3:klicovaSlova
Macrocycles; LC/MS; Cyclisation; Click reaction; 2-Azidobenzoate
n3:klicoveSlovo
n8:2-Azidobenzoate n8:Click%20reaction n8:Cyclisation n8:Macrocycles n8:LC%2FMS
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[B0297722B82E]
n3:nazevZdroje
Tetrahedron Letters
n3:obor
n15:CC
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n20:ME09057
n3:rokUplatneniVysledku
n5:2013
n3:svazekPeriodika
54
n3:tvurceVysledku
Hradilová, Ludmila Grepl, Martin Dvořáková, Barbora Hradil, Pavel
n3:wos
000315321600010
n3:zamer
n6:MSM6198959216
s:issn
0040-4039
s:numberOfPages
4
n11:doi
10.1016/j.tetlet.2012.12.076
n13:organizacniJednotka
15310