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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F13%3A33147371%21RIV14-MSM-15310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
A homemade fused-silica capillary dropping mercury electrode was used for the investigation of the adsorption behavior of a complex system by electrocapillary measurements. A mixture of soybean phospholipids, known as asolectin, was used for this purpose. The proposed setup with a fused-silica capillary electrode enables to observe aggregation and adsorption of asolectin aggregates at the mercury electrode surface and to determine the concentrations corresponding to the formation of asolectin micelles (critical micelle concentration, CMC) and liposomes (critical liposome concentration, CLC). Values of CMC (196.239.0 mg?L-1) and CLC (1360350 mg?L-1) were obtained from the dependence of drop time on the logarithm of asolectin concentration in phosphate buffer pH 7.0 within a concentration range from 1 to 50 mmol?L-1. A homemade fused-silica capillary dropping mercury electrode was used for the investigation of the adsorption behavior of a complex system by electrocapillary measurements. A mixture of soybean phospholipids, known as asolectin, was used for this purpose. The proposed setup with a fused-silica capillary electrode enables to observe aggregation and adsorption of asolectin aggregates at the mercury electrode surface and to determine the concentrations corresponding to the formation of asolectin micelles (critical micelle concentration, CMC) and liposomes (critical liposome concentration, CLC). Values of CMC (196.239.0 mg?L-1) and CLC (1360350 mg?L-1) were obtained from the dependence of drop time on the logarithm of asolectin concentration in phosphate buffer pH 7.0 within a concentration range from 1 to 50 mmol?L-1.
dcterms:title
Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements
skos:prefLabel
Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements Fused-Silica Capillary Dropping Mercury Electrode for Electrocapillary Measurements
skos:notation
RIV/61989592:15310/13:33147371!RIV14-MSM-15310___
n19:predkladatel
n20:orjk%3A15310
n3:aktivita
n14:P
n3:aktivity
P(ED2.1.00/03.0058), P(EE2.3.20.0018)
n3:cisloPeriodika
1
n3:dodaniDat
n7:2014
n3:domaciTvurceVysledku
n16:2949857 n16:1077074 n16:2670003 n16:3257010
n3:druhVysledku
n15:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
76053
n3:idVysledku
RIV/61989592:15310/13:33147371
n3:jazykVysledku
n17:eng
n3:klicovaSlova
Surfactants; Phospholipids; Electrocapillary measurement; Dropping mercury electrode; Aggregation
n3:klicoveSlovo
n12:Phospholipids n12:Electrocapillary%20measurement n12:Dropping%20mercury%20electrode n12:Aggregation n12:Surfactants
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[E6A0584997B4]
n3:nazevZdroje
Electroanalysis
n3:obor
n11:CB
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
4
n3:projekt
n10:ED2.1.00%2F03.0058 n10:EE2.3.20.0018
n3:rokUplatneniVysledku
n7:2013
n3:svazekPeriodika
25
n3:tvurceVysledku
Švecová, Hana Barták, Petr Součková, Jitka Skopalová, Jana
n3:wos
000313807600022
s:issn
1040-0397
s:numberOfPages
5
n4:doi
10.1002/elan.201200382
n6:organizacniJednotka
15310