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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F13%3A33146218%21RIV14-MSM-15310___
rdf:type
skos:Concept n18:Vysledek
rdfs:seeAlso
http://onlinelibrary.wiley.com/doi/10.1002/ejic.201201038/pdf
dcterms:description
Iron(III) mononuclear complexes that involve pentadentate Schiff base ligands and chlorido, azido, cyanido, cyanato, thiocyanato, or selenocyanato coligands were synthesized, structurally characterized, and subjected to a magnetochemical investigation. The Schiff bases were derived either from 5-chlorosalicylaldehyde or the 2-hydroxyacetonaphthone analogues by using an asymmetric 1,6-diamino-4-azahexane. A polymorphism that originated from different pentadentate ligand conformations on the iron center or different arrangements of noncovalent contacts was detected for the thiocyanato complexes. The central iron(III) atoms are mostly in the high-spin states, except for that with the coordinated cyanido ligand. Four complexes that contain the thiocyanato or selenocyanato ligand exhibit spin crossover, centered at the critical temperature (T-c) of 42, 114, 282, and 293 K, respectively. The magnetic data of all compounds were analyzed using the spin Hamiltonian formalism including the zero-field splitting (ZFS) term, and in the case of the spin-crossover compounds, the Ising-like model with vibrations was applied. Iron(III) mononuclear complexes that involve pentadentate Schiff base ligands and chlorido, azido, cyanido, cyanato, thiocyanato, or selenocyanato coligands were synthesized, structurally characterized, and subjected to a magnetochemical investigation. The Schiff bases were derived either from 5-chlorosalicylaldehyde or the 2-hydroxyacetonaphthone analogues by using an asymmetric 1,6-diamino-4-azahexane. A polymorphism that originated from different pentadentate ligand conformations on the iron center or different arrangements of noncovalent contacts was detected for the thiocyanato complexes. The central iron(III) atoms are mostly in the high-spin states, except for that with the coordinated cyanido ligand. Four complexes that contain the thiocyanato or selenocyanato ligand exhibit spin crossover, centered at the critical temperature (T-c) of 42, 114, 282, and 293 K, respectively. The magnetic data of all compounds were analyzed using the spin Hamiltonian formalism including the zero-field splitting (ZFS) term, and in the case of the spin-crossover compounds, the Ising-like model with vibrations was applied.
dcterms:title
Spin Crossover in Iron(III) Complexes with Pentadentate Schiff Base Ligands and Pseudohalido Coligands Spin Crossover in Iron(III) Complexes with Pentadentate Schiff Base Ligands and Pseudohalido Coligands
skos:prefLabel
Spin Crossover in Iron(III) Complexes with Pentadentate Schiff Base Ligands and Pseudohalido Coligands Spin Crossover in Iron(III) Complexes with Pentadentate Schiff Base Ligands and Pseudohalido Coligands
skos:notation
RIV/61989592:15310/13:33146218!RIV14-MSM-15310___
n18:predkladatel
n21:orjk%3A15310
n3:aktivita
n13:P
n3:aktivity
P(ED2.1.00/03.0058), P(EE2.3.20.0017)
n3:cisloPeriodika
5-6
n3:dodaniDat
n16:2014
n3:domaciTvurceVysledku
n7:2321459 n7:3770265
n3:druhVysledku
n6:J
n3:duvernostUdaju
n5:S
n3:entitaPredkladatele
n20:predkladatel
n3:idSjednocenehoVysledku
107056
n3:idVysledku
RIV/61989592:15310/13:33146218
n3:jazykVysledku
n15:eng
n3:klicovaSlova
Pseudohalides; Schiff bases; Ligand design; Spin crossover; Iron
n3:klicoveSlovo
n4:Schiff%20bases n4:Pseudohalides n4:Spin%20crossover n4:Ligand%20design n4:Iron
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[9C1EEF2DA7D1]
n3:nazevZdroje
European Journal of Inorganic Chemistry
n3:obor
n14:CA
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
7
n3:projekt
n8:EE2.3.20.0017 n8:ED2.1.00%2F03.0058
n3:rokUplatneniVysledku
n16:2013
n3:svazekPeriodika
2013
n3:tvurceVysledku
Krueger, Christoph Renz, Franz Boča, Roman Trávníček, Zdeněk Nemec, Ivan Augustin, Peter Oshio, Hiroki
n3:wos
000316390900035
s:issn
1434-1948
s:numberOfPages
14
n9:doi
10.1002/ejic.201201038
n17:organizacniJednotka
15310