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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F12%3A33140878%21RIV13-MSM-15310___
rdf:type
n17:Vysledek skos:Concept
dcterms:description
A series of Ni(II) dithiolenes derived from maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt), and toluene-3,4-dithiol (tdt) with potentially tridentate P,P,P-ligands bis(2-diphenylphosphino-ethyl) phenylphosphine (triphosI) and 1,1,1-tris-(diphenylphosphino-methyl)-ethane (triphosII) of the [Ni(P, P, P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, and conductivity measurements. Single-crystal X-ray analysis of [Ni(triphosI)(mnt)] confirmed a planar geometry of NiP2S2 chromophore (one of P-atoms is not coordinated). Possible practical applications such as the use of these compounds as anticholinesterase agents were evaluated. A series of Ni(II) dithiolenes derived from maleonitriledithiol (mnt), benzene-1,2-dithiol (bdt), and toluene-3,4-dithiol (tdt) with potentially tridentate P,P,P-ligands bis(2-diphenylphosphino-ethyl) phenylphosphine (triphosI) and 1,1,1-tris-(diphenylphosphino-methyl)-ethane (triphosII) of the [Ni(P, P, P)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical, and conductivity measurements. Single-crystal X-ray analysis of [Ni(triphosI)(mnt)] confirmed a planar geometry of NiP2S2 chromophore (one of P-atoms is not coordinated). Possible practical applications such as the use of these compounds as anticholinesterase agents were evaluated.
dcterms:title
Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands
skos:prefLabel
Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands Planar Ni(II) 1,2-dithiolenes involving tridentate P-donor ligands
skos:notation
RIV/61989592:15310/12:33140878!RIV13-MSM-15310___
n17:predkladatel
n18:orjk%3A15310
n3:aktivita
n15:I n15:V n15:Z
n3:aktivity
I, V, Z(MO0FVZ0000604)
n3:cisloPeriodika
1
n3:dodaniDat
n20:2013
n3:domaciTvurceVysledku
n14:2068079
n3:druhVysledku
n16:J
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n7:predkladatel
n3:idSjednocenehoVysledku
158799
n3:idVysledku
RIV/61989592:15310/12:33140878
n3:jazykVysledku
n5:eng
n3:klicovaSlova
Inhibitor; Cholinesterase; X-ray structure; Dithiolenes; Nickel(II)
n3:klicoveSlovo
n4:Nickel%28II%29 n4:Inhibitor n4:X-ray%20structure n4:Dithiolenes n4:Cholinesterase
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[5EC933487460]
n3:nazevZdroje
Journal of Coordination Chemistry
n3:obor
n11:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
7
n3:rokUplatneniVysledku
n20:2012
n3:svazekPeriodika
65
n3:tvurceVysledku
Dlhan, Lubor Kozisek, Jozef Herich, Peter Kameníček, Jiří Holas, Ondrej Kuca, Kamil Pohanka, Miroslav
n3:wos
000302034300014
n3:zamer
n10:MO0FVZ0000604
s:issn
0095-8972
s:numberOfPages
9
n6:doi
10.1080/00958972.2011.644543
n13:organizacniJednotka
15310