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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F11%3A33118057%21RIV12-MSM-15310___
rdf:type
skos:Concept n18:Vysledek
dcterms:description
The preparation and electropolymerization of a new porphyrin monomer with an amino group connecting the porphyrin core and aniline unit were studied. Cyclic voltammetry, FTIR spectroscopy, and a tandem quadrupole/time of flight mass spectrometry with matrix-assisted laser desorption/ionization source (MALDI-QqTOF) were used for the characterization of poly(5-(4'-aminophenylamino)-10,20-diphenylporphyrin) (PAPADPP). The PAPADPP formed a smooth layer on the Indium tin oxide (ITO) electrode and grew perpendicular to the electrode surface. An oligonucleotide (ODN)-probe was physisorbed onto the PAPADPP film and tested for hybridization with complementary and noncomplementary ODN segments. Biological recognition was monitored by comparison of the electrochemical signals (cyclic voltammogram) from single and double strand state oligonucleotides. The morphology of the physisorbed ODN-probe and its hybridization were observed on ITO electrodes using AFM and SEM. The preparation and electropolymerization of a new porphyrin monomer with an amino group connecting the porphyrin core and aniline unit were studied. Cyclic voltammetry, FTIR spectroscopy, and a tandem quadrupole/time of flight mass spectrometry with matrix-assisted laser desorption/ionization source (MALDI-QqTOF) were used for the characterization of poly(5-(4'-aminophenylamino)-10,20-diphenylporphyrin) (PAPADPP). The PAPADPP formed a smooth layer on the Indium tin oxide (ITO) electrode and grew perpendicular to the electrode surface. An oligonucleotide (ODN)-probe was physisorbed onto the PAPADPP film and tested for hybridization with complementary and noncomplementary ODN segments. Biological recognition was monitored by comparison of the electrochemical signals (cyclic voltammogram) from single and double strand state oligonucleotides. The morphology of the physisorbed ODN-probe and its hybridization were observed on ITO electrodes using AFM and SEM.
dcterms:title
Electrochemical Polymerization and Investigation of Properties of Poly(5-(4''-aminophenylamino)-10,20-diphenylporphyrin) Electrochemical Polymerization and Investigation of Properties of Poly(5-(4''-aminophenylamino)-10,20-diphenylporphyrin)
skos:prefLabel
Electrochemical Polymerization and Investigation of Properties of Poly(5-(4''-aminophenylamino)-10,20-diphenylporphyrin) Electrochemical Polymerization and Investigation of Properties of Poly(5-(4''-aminophenylamino)-10,20-diphenylporphyrin)
skos:notation
RIV/61989592:15310/11:33118057!RIV12-MSM-15310___
n18:predkladatel
n20:orjk%3A15310
n3:aktivita
n4:Z
n3:aktivity
Z(MSM6198959216)
n3:cisloPeriodika
5
n3:dodaniDat
n8:2012
n3:domaciTvurceVysledku
n15:5646634 n15:8390924
n3:druhVysledku
n10:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
197039
n3:idVysledku
RIV/61989592:15310/11:33118057
n3:jazykVysledku
n9:eng
n3:klicovaSlova
Biosensors; Conducting polymers; Electropolymerization; Porphyrin
n3:klicoveSlovo
n7:Conducting%20polymers n7:Electropolymerization n7:Porphyrin n7:Biosensors
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[9AAAE9B88B4B]
n3:nazevZdroje
Electroanalysis
n3:obor
n19:CD
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
9
n3:rokUplatneniVysledku
n8:2011
n3:svazekPeriodika
23
n3:tvurceVysledku
Uygun, Aysegul Frankhauser, Anita Fields, Kimberley Myjavcová, Renata Yavuz, Ayse Gul Bednář, Petr Bhethanbotla, Venkat Ruppel, Joshua Zhang, X. Peter
n3:wos
000290487600016
n3:zamer
n13:MSM6198959216
s:issn
1040-0397
s:numberOfPages
10
n14:doi
10.1002/elan.201000609
n16:organizacniJednotka
15310