This HTML5 document contains 49 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n21http://localhost/temp/predkladatel/
n17http://linked.opendata.cz/resource/domain/vavai/projekt/
n4http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n14http://linked.opendata.cz/resource/domain/vavai/subjekt/
n13http://linked.opendata.cz/ontology/domain/vavai/
n8http://linked.opendata.cz/resource/domain/vavai/zamer/
n9http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61989592%3A15310%2F11%3A33116864%21RIV13-MSM-15310___/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n5http://bibframe.org/vocab/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n11http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n19http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n16http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n7http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n20http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n12http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n15http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F11%3A33116864%21RIV13-MSM-15310___
rdf:type
n13:Vysledek skos:Concept
dcterms:description
Fourteen octahedral Ni(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X.yH2O {ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4- (1-8; y = 0) or [FeCl4]- (9-14; y = 0 for 9-12, 1 for 13 and 0.5 for 14) was prepared by the oxidation of the corresponding Ni(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent Ni(IV)S6 core, were characterized by elemental analysis (C, H, N. Cl and Ni), UV-Vis and FTIR spectroscopy, thermal analysis and magnetochemical and conductivity measurements. The X-ray structure of {Ni(hmidtc)3][FeCl4] (9) was determined and this revealed slightly distorted octahedral and tetrahedral geometries within the complex cations, and anions, respectively. Moreover, the formal oxidation state of iron in (FeCl4]- as well as the coordination geometry in its vicinity was also proved by 57Fe Mossbauer spectroscopy in the case of 9. Fourteen octahedral Ni(IV) dithiocarbamato complexes of the general formula [Ni(ndtc)3]X.yH2O {ndtc stands for the appropriate dithiocarbamate anion, X stands for ClO4- (1-8; y = 0) or [FeCl4]- (9-14; y = 0 for 9-12, 1 for 13 and 0.5 for 14) was prepared by the oxidation of the corresponding Ni(II) complexes, i.e. [Ni(ndtc)2], with NOClO4 or FeCl3. The complexes, involving a high-valent Ni(IV)S6 core, were characterized by elemental analysis (C, H, N. Cl and Ni), UV-Vis and FTIR spectroscopy, thermal analysis and magnetochemical and conductivity measurements. The X-ray structure of {Ni(hmidtc)3][FeCl4] (9) was determined and this revealed slightly distorted octahedral and tetrahedral geometries within the complex cations, and anions, respectively. Moreover, the formal oxidation state of iron in (FeCl4]- as well as the coordination geometry in its vicinity was also proved by 57Fe Mossbauer spectroscopy in the case of 9.
dcterms:title
Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4] Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]
skos:prefLabel
Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4] Nickel(IV) dithiocarbamato complexes of the [Ni(ndtc)3]X type: X-ray structure of [Ni(hmidtc)3][FeCl4]
skos:notation
RIV/61989592:15310/11:33116864!RIV13-MSM-15310___
n13:predkladatel
n14:orjk%3A15310
n3:aktivita
n16:Z n16:P
n3:aktivity
P(ED2.1.00/03.0058), P(EE2.3.20.0017), Z(MSM6198959218)
n3:cisloPeriodika
17
n3:dodaniDat
n15:2013
n3:domaciTvurceVysledku
n4:3214915 n4:2321459 n4:8392013
n3:druhVysledku
n20:J
n3:duvernostUdaju
n19:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
216024
n3:idVysledku
RIV/61989592:15310/11:33116864
n3:jazykVysledku
n7:eng
n3:klicovaSlova
Spectroscopy; X-ray structure; Dithiocarbamate; Nickel(IV) complexes
n3:klicoveSlovo
n11:Spectroscopy n11:Nickel%28IV%29%20complexes n11:Dithiocarbamate n11:X-ray%20structure
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[12FBA96A74BB]
n3:nazevZdroje
Polyhedron
n3:obor
n12:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
4
n3:projekt
n17:ED2.1.00%2F03.0058 n17:EE2.3.20.0017
n3:rokUplatneniVysledku
n15:2011
n3:svazekPeriodika
30
n3:tvurceVysledku
Peterek, Tomáš Štarha, Pavel Pastorek, Richard Trávníček, Zdeněk
n3:wos
000296996500006
n3:zamer
n8:MSM6198959218
s:issn
0277-5387
s:numberOfPages
6
n5:doi
10.1016/j.poly.2011.08.022
n21:organizacniJednotka
15310