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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F11%3A10222342%21RIV12-MSM-15310___
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Syntheses and crystal structures of nickel(II) complexes containing teta (teta = N,N0-bis(2-aminoethyl)ethane-1,2-diamine) as a tetradentate blocking ligand and cyanidometallic bridging complexes are described. The complexes [Ni(teta)(cis-l2-Ni(CN)4)] (1) and [{Ni(teta)}3(l6-Co(CN)6)] (ClO4)3 (2) exhibit a 1D-polymeric structure whereas the heterometallic trinuclear complex [Ni(teta)(l1-Ag(CN)2)2] (3) forms a unique network. The weak antiferromagnetic exchange was found in polymeric species 1 and 2 by analyzing the magnetic data with several models in which either only susceptibility was treated or simultaneous fitting of temperature and magnetic field dependences of the magnetization was applied using the finite-size closed ring approach. Moreover, an effect of the zero-field splitting phenomenon(ZFS) was considered for 2 by advanced modeling of magnetic properties for varying axial ZFS parameter/isotropic exchange (D/J) ratios. Syntheses and crystal structures of nickel(II) complexes containing teta (teta = N,N0-bis(2-aminoethyl)ethane-1,2-diamine) as a tetradentate blocking ligand and cyanidometallic bridging complexes are described. The complexes [Ni(teta)(cis-l2-Ni(CN)4)] (1) and [{Ni(teta)}3(l6-Co(CN)6)] (ClO4)3 (2) exhibit a 1D-polymeric structure whereas the heterometallic trinuclear complex [Ni(teta)(l1-Ag(CN)2)2] (3) forms a unique network. The weak antiferromagnetic exchange was found in polymeric species 1 and 2 by analyzing the magnetic data with several models in which either only susceptibility was treated or simultaneous fitting of temperature and magnetic field dependences of the magnetization was applied using the finite-size closed ring approach. Moreover, an effect of the zero-field splitting phenomenon(ZFS) was considered for 2 by advanced modeling of magnetic properties for varying axial ZFS parameter/isotropic exchange (D/J) ratios.
dcterms:title
Heterobimetallic assemblies of Ni(II) complexes with a tetradentate amine ligand and diamagnetic cyanidometallates Heterobimetallic assemblies of Ni(II) complexes with a tetradentate amine ligand and diamagnetic cyanidometallates
skos:prefLabel
Heterobimetallic assemblies of Ni(II) complexes with a tetradentate amine ligand and diamagnetic cyanidometallates Heterobimetallic assemblies of Ni(II) complexes with a tetradentate amine ligand and diamagnetic cyanidometallates
skos:notation
RIV/61989592:15310/11:10222342!RIV12-MSM-15310___
n11:predkladatel
n19:orjk%3A15310
n3:aktivita
n9:P n9:Z
n3:aktivity
P(ED2.1.00/03.0058), Z(MSM6198959218)
n3:cisloPeriodika
1
n3:dodaniDat
n8:2012
n3:domaciTvurceVysledku
n16:3770265 n16:2321459 n16:6407226
n3:druhVysledku
n4:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
201943
n3:idVysledku
RIV/61989592:15310/11:10222342
n3:jazykVysledku
n5:eng
n3:klicovaSlova
Heterobimetallic complex, Nickel(II) complex, X-ray structure, Magnetism, Cyanidometallate
n3:klicoveSlovo
n6:Nickel%28II%29%20complex n6:Cyanidometallate n6:Magnetism n6:Heterobimetallic%20complex n6:X-ray%20structure
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[95D36542C5F1]
n3:nazevZdroje
Inorganica Chimica Acta
n3:obor
n13:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
8
n3:projekt
n14:ED2.1.00%2F03.0058
n3:rokUplatneniVysledku
n8:2011
n3:svazekPeriodika
366
n3:tvurceVysledku
Herchel, Radovan Fuess, Hartmut Nemec, Ivan Dľháň, Ľubor Trávníček, Zdeněk Svoboda, Ingrid Boča, Roman Matelková, Kristína
n3:wos
000285994200049
n3:zamer
n15:MSM6198959218
s:issn
0020-1693
s:numberOfPages
7
n20:organizacniJednotka
15310