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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F11%3A10222340%21RIV12-MSM-15310___
rdf:type
skos:Concept n12:Vysledek
dcterms:description
The nickel(II) complexes of the compositions [Ni(hmidtc)(bpy)2]ClO4 (I), [Ni(hmidtc)(phen)2]ClO4 (II),[Ni(hmidtc)(phen)2]SCN (III), [Ni(hmidtc)(phen)2]PF6 (IV), [Ni(hmidtc)(phen)2]BPh4 (V), [Ni(hmidtc)(phen)2]AcO2H2O (VI) and [Ni(hmidtc)(phen)2]BrH2O (VII), involving a combination of one hexamethyleneimine-dithiocarbamate anion (hmidtc) and two bidentate N,N-donor ligands (2,20-bipyridine(bpy) for I or 1,10-phenanthroline (phen) for II-VII), have been prepared. The compounds were characterized by elemental analysis, molar conductivity measurements, UV-Vis and IR spectroscopy, magnetochemical measurements and thermal analysis. A single-crystal X-ray analysis of the complex I revealed a distorted octahedral geometry with the nickel(II) ion coordinated by four nitrogen atoms(from two bidentate-coordinated bpy molecules) and two sulfur atoms (from one bidentate-coordinated hmidtc anion), together giving an NiN4S2 donor set. The nickel(II) complexes of the compositions [Ni(hmidtc)(bpy)2]ClO4 (I), [Ni(hmidtc)(phen)2]ClO4 (II),[Ni(hmidtc)(phen)2]SCN (III), [Ni(hmidtc)(phen)2]PF6 (IV), [Ni(hmidtc)(phen)2]BPh4 (V), [Ni(hmidtc)(phen)2]AcO2H2O (VI) and [Ni(hmidtc)(phen)2]BrH2O (VII), involving a combination of one hexamethyleneimine-dithiocarbamate anion (hmidtc) and two bidentate N,N-donor ligands (2,20-bipyridine(bpy) for I or 1,10-phenanthroline (phen) for II-VII), have been prepared. The compounds were characterized by elemental analysis, molar conductivity measurements, UV-Vis and IR spectroscopy, magnetochemical measurements and thermal analysis. A single-crystal X-ray analysis of the complex I revealed a distorted octahedral geometry with the nickel(II) ion coordinated by four nitrogen atoms(from two bidentate-coordinated bpy molecules) and two sulfur atoms (from one bidentate-coordinated hmidtc anion), together giving an NiN4S2 donor set.
dcterms:title
Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands
skos:prefLabel
Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands Octahedral nickel(II) hexamethyleneimine-dithiocarbamato complexes involving bidentate N,N-donor ligands
skos:notation
RIV/61989592:15310/11:10222340!RIV12-MSM-15310___
n12:predkladatel
n13:orjk%3A15310
n5:aktivita
n8:Z n8:P
n5:aktivity
P(ED2.1.00/03.0058), Z(MSM6198959218)
n5:cisloPeriodika
1
n5:dodaniDat
n14:2012
n5:domaciTvurceVysledku
n6:3214915 n6:8392013 n6:2321459
n5:druhVysledku
n19:J
n5:duvernostUdaju
n7:S
n5:entitaPredkladatele
n20:predkladatel
n5:idSjednocenehoVysledku
217535
n5:idVysledku
RIV/61989592:15310/11:10222340
n5:jazykVysledku
n16:eng
n5:klicovaSlova
Nickel(II) complexes, Hexamethyleneimine, Dithiocarbamate, X-ray structure
n5:klicoveSlovo
n10:Dithiocarbamate n10:X-ray%20structure n10:Hexamethyleneimine n10:Nickel%28II%29%20complexes
n5:kodStatuVydavatele
NL - Nizozemsko
n5:kontrolniKodProRIV
[534AC810F6E8]
n5:nazevZdroje
Inorganica Chimica Acta
n5:obor
n11:CA
n5:pocetDomacichTvurcuVysledku
3
n5:pocetTvurcuVysledku
3
n5:projekt
n18:ED2.1.00%2F03.0058
n5:rokUplatneniVysledku
n14:2011
n5:svazekPeriodika
373
n5:tvurceVysledku
Štarha, Pavel Pastorek, Richard Trávníček, Zdeněk
n5:wos
000291244600042
n5:zamer
n15:MSM6198959218
s:issn
0020-1693
s:numberOfPages
5
n9:organizacniJednotka
15310