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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F10%3A10215835%21RIV11-GA0-15310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Stoichoimetric graphene fluoride monolayers are obtained in a single step by the liquid-phase exfoliation of graphite fluoride with sulfolane. Comparative quantum mechanical calculations reveal that graphene fluoride is the most thermodynamically stable of five studied hypothetical graphene derivatives; graphane, graphene fluoride, bromide, chloride, and iodide. The graphene fluoride is transformed into graphene via graphene iodide, a spontaneously decomposing intermediate. The calculated bandgaps of graphene halides vary from zero for graphene bromide to 3.1 eV for graphene fluoride. It is possible to design the electronic properties of such two-dimensional crystals. Stoichoimetric graphene fluoride monolayers are obtained in a single step by the liquid-phase exfoliation of graphite fluoride with sulfolane. Comparative quantum mechanical calculations reveal that graphene fluoride is the most thermodynamically stable of five studied hypothetical graphene derivatives; graphane, graphene fluoride, bromide, chloride, and iodide. The graphene fluoride is transformed into graphene via graphene iodide, a spontaneously decomposing intermediate. The calculated bandgaps of graphene halides vary from zero for graphene bromide to 3.1 eV for graphene fluoride. It is possible to design the electronic properties of such two-dimensional crystals.
dcterms:title
Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene
skos:prefLabel
Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene Graphene Fluoride: A Stable Stoichiometric Graphene Derivative and its Chemical Conversion to Graphene
skos:notation
RIV/61989592:15310/10:10215835!RIV11-GA0-15310___
n4:aktivita
n15:P n15:Z
n4:aktivity
P(1M0512), P(ED2.1.00/03.0058), P(GAP208/10/1742), P(LC512), Z(MSM6198959218)
n4:cisloPeriodika
24
n4:dodaniDat
n16:2011
n4:domaciTvurceVysledku
n6:3151948 n6:5772133 n6:7008686 n6:8452148 n6:9251189
n4:druhVysledku
n13:J
n4:duvernostUdaju
n18:S
n4:entitaPredkladatele
n19:predkladatel
n4:idSjednocenehoVysledku
260981
n4:idVysledku
RIV/61989592:15310/10:10215835
n4:jazykVysledku
n8:eng
n4:klicovaSlova
graphane; fluorographene; DFT; bandgap; Graphene
n4:klicoveSlovo
n17:Graphene n17:DFT n17:fluorographene n17:graphane n17:bandgap
n4:kodStatuVydavatele
DE - Spolková republika Německo
n4:kontrolniKodProRIV
[AF7487A42818]
n4:nazevZdroje
Small
n4:obor
n10:CF
n4:pocetDomacichTvurcuVysledku
5
n4:pocetTvurcuVysledku
10
n4:projekt
n9:ED2.1.00%2F03.0058 n9:1M0512 n9:LC512 n9:GAP208%2F10%2F1742
n4:rokUplatneniVysledku
n16:2010
n4:svazekPeriodika
6
n4:tvurceVysledku
ZBOŘIL, RADEK Trapalis, Christos ŠAFÁŘOVÁ, Klára KARLICKÝ, František OTYEPKA, Michal JANČÍK, Dalibor Bourlinos, Athanasios B. Steriotis, Theodore A. Stubos, Athanasios K. Georgakilas, Vasilios
n4:zamer
n5:MSM6198959218
s:issn
1613-6810
s:numberOfPages
7
n3:organizacniJednotka
15310