This HTML5 document contains 49 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n17http://localhost/temp/predkladatel/
n12http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n5http://linked.opendata.cz/resource/domain/vavai/projekt/
n7http://linked.opendata.cz/ontology/domain/vavai/
n16http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n4http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n15http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61989592%3A15310%2F10%3A10215446%21RIV11-MSM-15310___/
n6http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n9http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n19http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n14http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n18http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n11http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n10http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F10%3A10215446%21RIV11-MSM-15310___
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Applicability of the previously described rearrangement of 2-oxo-2-phenylethyl 2-amino?benzoate leading to 2-phenyl-2-hydroxymethyl-2,3-dihydroquinazolin-4(1H)-one has been studied. To test the limits of the reaction, various starting compounds such as 2-oxopropyl 2-aminobenzoate, 2-oxo-2-phenylethyl 2-aminobenzoate and 3,3-dimethyl-2-oxobutyl 2-aminobenzoate as well as some of their corresponding N-methyl and N-phenyl analogues were used. The structure-reactivity dependence was observed giving the expected products only in specific cases and in limited yields. Structure of the dihydroquinazolin-4(1H)-one skeleton was unambiguously confirmed with use of X-ray analysis of two selected compounds. Finally, an alternative way for the preparation of the desired derivatives was developed. Applicability of the previously described rearrangement of 2-oxo-2-phenylethyl 2-amino?benzoate leading to 2-phenyl-2-hydroxymethyl-2,3-dihydroquinazolin-4(1H)-one has been studied. To test the limits of the reaction, various starting compounds such as 2-oxopropyl 2-aminobenzoate, 2-oxo-2-phenylethyl 2-aminobenzoate and 3,3-dimethyl-2-oxobutyl 2-aminobenzoate as well as some of their corresponding N-methyl and N-phenyl analogues were used. The structure-reactivity dependence was observed giving the expected products only in specific cases and in limited yields. Structure of the dihydroquinazolin-4(1H)-one skeleton was unambiguously confirmed with use of X-ray analysis of two selected compounds. Finally, an alternative way for the preparation of the desired derivatives was developed.
dcterms:title
Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route
skos:prefLabel
Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route Study of anthranilate cyclisation to 2-hydroxymethyl-2,3-dihydro-quinazolin-4(1H)-ones and an alternative synthetic route
skos:notation
RIV/61989592:15310/10:10215446!RIV11-MSM-15310___
n4:aktivita
n14:Z n14:P
n4:aktivity
P(ME09057), Z(MSM6198959216)
n4:cisloPeriodika
10
n4:dodaniDat
n10:2011
n4:domaciTvurceVysledku
n12:5110386 n12:8225583 n12:1759256 n12:3170594
n4:druhVysledku
n18:J
n4:duvernostUdaju
n9:S
n4:entitaPredkladatele
n15:predkladatel
n4:idSjednocenehoVysledku
290731
n4:idVysledku
RIV/61989592:15310/10:10215446
n4:jazykVysledku
n19:eng
n4:klicovaSlova
Dihydroquinazolinone, rearrangement, X-ray, condensation
n4:klicoveSlovo
n6:Dihydroquinazolinone n6:rearrangement n6:X-ray n6:condensation
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[D07B777498A5]
n4:nazevZdroje
Arkivoc
n4:obor
n11:CC
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
6
n4:projekt
n5:ME09057
n4:rokUplatneniVysledku
n10:2010
n4:svazekPeriodika
NA
n4:tvurceVysledku
Soural, Miroslav Funk, Petr Kvapil, L. Hradil, Pavel Hlaváč, Jan Bertolasi, V.
n4:wos
000282480400021
n4:zamer
n16:MSM6198959216
s:issn
1424-6376
s:numberOfPages
11
n17:organizacniJednotka
15310