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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F09%3A00010181%21RIV10-MSM-15310___
rdf:type
skos:Concept n18:Vysledek
dcterms:description
Reactions of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (H(4)edte) with MnCl2 center dot 4H(2)O or FeCl3 center dot 6H(2)O in MeOH or MeCN with different bases yield four butterfly-like tetranuclear clusters with fused defective dicubane M4O6 cores: [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot MeCN (1) (H(4)edte = N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine, H(3)thme = 1,1,1-tris(hydroxymethyl)ethane), [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot 2MeOH (2), [Fe-4(III)(mu(4)-Hedte)(2)(N-3)(6)]center dot 2MeCN (3) and [Fe-4(III)(mu(4)-edte)(2)-(N-3)(4)(MeOH)(2)] (4). Both 1 and 3 crystallize in the triclinic space group P (1) over bar, while 2 and 4 crystallize in the monoclinic space group P2(1)/c and P2(1)/n, respectively. The hexadentate Hedte(3-) ligand in 1-3, and the edte(4-) ligand in 4 acts in a similar mu(4):eta(1):eta(1):eta(1):eta(2):eta(2):eta(3) coordination mode to bridge four metal ions into butterfly-like tetranuclear clusters with fused Reactions of N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine (H(4)edte) with MnCl2 center dot 4H(2)O or FeCl3 center dot 6H(2)O in MeOH or MeCN with different bases yield four butterfly-like tetranuclear clusters with fused defective dicubane M4O6 cores: [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot MeCN (1) (H(4)edte = N,N,N',N'-tetrakis(2-hydroxyethyl)ethylenediamine, H(3)thme = 1,1,1-tris(hydroxymethyl)ethane), [(Mn2Mn2IV)-Mn-II(mu(4)-Hedte)(2)(thme)(2)]center dot 2MeOH (2), [Fe-4(III)(mu(4)-Hedte)(2)(N-3)(6)]center dot 2MeCN (3) and [Fe-4(III)(mu(4)-edte)(2)-(N-3)(4)(MeOH)(2)] (4). Both 1 and 3 crystallize in the triclinic space group P (1) over bar, while 2 and 4 crystallize in the monoclinic space group P2(1)/c and P2(1)/n, respectively. The hexadentate Hedte(3-) ligand in 1-3, and the edte(4-) ligand in 4 acts in a similar mu(4):eta(1):eta(1):eta(1):eta(2):eta(2):eta(3) coordination mode to bridge four metal ions into butterfly-like tetranuclear clusters with fused
dcterms:title
High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism
skos:prefLabel
High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism High-spin tetranuclear (Mn2Mn2IV)-Mn-II clusters with unique Mn(II)-Mn(IV) magnetic exchange: synthesis, structures and magnetism
skos:notation
RIV/61989592:15310/09:00010181!RIV10-MSM-15310___
n3:aktivita
n15:Z
n3:aktivity
Z(MSM6198959218)
n3:cisloPeriodika
17
n3:dodaniDat
n7:2010
n3:domaciTvurceVysledku
n8:6407226
n3:druhVysledku
n10:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n9:predkladatel
n3:idSjednocenehoVysledku
317180
n3:idVysledku
RIV/61989592:15310/09:00010181
n3:jazykVysledku
n5:eng
n3:klicovaSlova
SINGLE-MOLECULE MAGNETS; WATER OXIDATION CENTER; CRYSTAL-STRUCTURES; CARBOXYLATE CLUSTERS; MANGANESE COMPLEXES; BUILDING-BLOCKS; HIGH-NUCLEARITY; GROUND-STATE; X-RAY; LIGANDS
n3:klicoveSlovo
n6:MANGANESE%20COMPLEXES n6:BUILDING-BLOCKS n6:CRYSTAL-STRUCTURES n6:HIGH-NUCLEARITY n6:LIGANDS n6:WATER%20OXIDATION%20CENTER n6:CARBOXYLATE%20CLUSTERS n6:X-RAY n6:SINGLE-MOLECULE%20MAGNETS n6:GROUND-STATE
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[BF5CF4E39991]
n3:nazevZdroje
Dalton Transactions
n3:obor
n11:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n7:2009
n3:svazekPeriodika
2009
n3:tvurceVysledku
Tong, Ming-Liang Zhou, Ai-Ju Leng, Ji-Dong Liu, Jun-Liang Herchel, Radovan
n3:zamer
n13:MSM6198959218
s:issn
1477-9226
s:numberOfPages
11
n17:organizacniJednotka
15310