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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F08%3A00009945%21RIV10-MSM-15310___
rdf:type
n16:Vysledek skos:Concept
dcterms:description
A series of planar Ni(II) dithiolenes derived from maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) with bidentate N,N-ligands (bpy = 2,2'-bipyridine; phen = 1,10-phenanthroline; nphen = 5-nitro-1,10-phenanthroline) of the [Ni(N,N)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(phen)(bdt)] confirmed a planar geometry of NiN2S2. Possible practical applications such as use for vulcanization catalytic agents and for their anticholinesterase activity were evaluated. A series of planar Ni(II) dithiolenes derived from maleonitriledithiole (mnt), benzene-1,2-dithiole (bdt) and 1-toluene-3,4-dithiole (tdt) with bidentate N,N-ligands (bpy = 2,2'-bipyridine; phen = 1,10-phenanthroline; nphen = 5-nitro-1,10-phenanthroline) of the [Ni(N,N)(dithiol)] type have been synthesized. The compounds have been characterized by elemental analysis, IR and electronic spectroscopies, magnetochemical and conductivity measurements. Single crystal X-ray analysis of [Ni(phen)(bdt)] confirmed a planar geometry of NiN2S2. Possible practical applications such as use for vulcanization catalytic agents and for their anticholinesterase activity were evaluated.
dcterms:title
Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands
skos:prefLabel
Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands Planar Ni(II) 1,2-dithiolenes involving bidentate N-donor ligands
skos:notation
RIV/61989592:15310/08:00009945!RIV10-MSM-15310___
n3:aktivita
n17:S n17:P
n3:aktivity
P(ME 865), S
n3:cisloPeriodika
22
n3:dodaniDat
n12:2010
n3:domaciTvurceVysledku
n6:7452802 n6:2068079
n3:druhVysledku
n18:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
386729
n3:idVysledku
RIV/61989592:15310/08:00009945
n3:jazykVysledku
n5:eng
n3:klicovaSlova
Nickel(II); N,S-ligands; Vulcanization agents; Cholinesterase; Inhibitor.
n3:klicoveSlovo
n15:Cholinesterase n15:Nickel%28II%29 n15:N n15:Inhibitor. n15:Vulcanization%20agents n15:S-ligands
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[077838892AF2]
n3:nazevZdroje
Journal of Coordination Chemistry
n3:obor
n8:CA
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
5
n3:projekt
n10:ME%20865
n3:rokUplatneniVysledku
n12:2008
n3:svazekPeriodika
61
n3:tvurceVysledku
Herich, Peter Jun, Daniel Olšovský, Milan Kuča, Kamil Kameníček, Jiří
s:issn
0095-8972
s:numberOfPages
9
n14:organizacniJednotka
15310