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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F08%3A00005501%21RIV10-MSM-15310___
rdf:type
skos:Concept n15:Vysledek
dcterms:description
The synthesis and characterization of ruthenium(II) arene complexes [(η6 arene)Ru(N,N)Cl]0/+, where N,N = 2,2´-bipyridine (bipy), 2,2´-bipyridine-3, 3´-diol (bipy(OH)2) or deprotonated 2,2´-bipyridine-3, 3´-diol (bipy(OH)O) as N,N-chelating ligand, arene = benzene (bz), indan (ind), biphenyl (bip), p-terphenyl (p-terp), tetrahydronaphthalene (thn), tetrahydroanthracene (tha) or dihydroanthracene (dha), are reported, including the X-ray crystal structures of [(η6-tha)Ru(bipy)Cl][PF6] (1), [(η6-tha)Ru(bipy(OH)O)Cl] (2) and [(n6 ind)Ru(bipy(OH)2)Cl][PF6] (8). Complexes 1 and 2 exibit CH (arene)/pi (bipy or bipy(OH)O) interactions. In the X-ray structure of protonated complex 8, the pyridine rings are twisted (by 17.31 C). In aqueous solution (pH = 2-10), only deprotonated (bipy(OH)O) forms are present. Hydrolysis of the complexes was relatively fast in aqueous solution (t = 4-15 min, 310 K). The synthesis and characterization of ruthenium(II) arene complexes [(η6 arene)Ru(N,N)Cl]0/+, where N,N = 2,2´-bipyridine (bipy), 2,2´-bipyridine-3, 3´-diol (bipy(OH)2) or deprotonated 2,2´-bipyridine-3, 3´-diol (bipy(OH)O) as N,N-chelating ligand, arene = benzene (bz), indan (ind), biphenyl (bip), p-terphenyl (p-terp), tetrahydronaphthalene (thn), tetrahydroanthracene (tha) or dihydroanthracene (dha), are reported, including the X-ray crystal structures of [(η6-tha)Ru(bipy)Cl][PF6] (1), [(η6-tha)Ru(bipy(OH)O)Cl] (2) and [(n6 ind)Ru(bipy(OH)2)Cl][PF6] (8). Complexes 1 and 2 exibit CH (arene)/pi (bipy or bipy(OH)O) interactions. In the X-ray structure of protonated complex 8, the pyridine rings are twisted (by 17.31 C). In aqueous solution (pH = 2-10), only deprotonated (bipy(OH)O) forms are present. Hydrolysis of the complexes was relatively fast in aqueous solution (t = 4-15 min, 310 K).
dcterms:title
The contrasting chemistry and cancer cell cytotoxicity of bipyridine and bipyridinediol ruthenium(II) arene complexes The contrasting chemistry and cancer cell cytotoxicity of bipyridine and bipyridinediol ruthenium(II) arene complexes
skos:prefLabel
The contrasting chemistry and cancer cell cytotoxicity of bipyridine and bipyridinediol ruthenium(II) arene complexes The contrasting chemistry and cancer cell cytotoxicity of bipyridine and bipyridinediol ruthenium(II) arene complexes
skos:notation
RIV/61989592:15310/08:00005501!RIV10-MSM-15310___
n3:aktivita
n9:P n9:Z
n3:aktivity
P(1QS500040581), P(IAA400040803), P(KAN200200651), P(LC06030), P(ME08017), P(NR8562), P(OC08003), Z(AV0Z50040507), Z(AV0Z50040702), Z(MSM6198959216)
n3:cisloPeriodika
24
n3:dodaniDat
n6:2010
n3:domaciTvurceVysledku
n14:4571932 n14:7988346
n3:druhVysledku
n10:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
361170
n3:idVysledku
RIV/61989592:15310/08:00005501
n3:jazykVysledku
n18:eng
n3:klicovaSlova
Ruthenium; anticancer drugs; DNA interactions
n3:klicoveSlovo
n11:anticancer%20drugs n11:DNA%20interactions n11:Ruthenium
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[4A22E8813900]
n3:nazevZdroje
Inorganic Chemistry
n3:obor
n19:CA
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
12
n3:projekt
n4:NR8562 n4:ME08017 n4:IAA400040803 n4:OC08003 n4:KAN200200651 n4:1QS500040581 n4:LC06030
n3:rokUplatneniVysledku
n6:2008
n3:svazekPeriodika
47
n3:tvurceVysledku
Deeth, J.R.. Bugarcic, Tijana Kašpárková, Jana Johnstone, R.D.L. Heringová, Pavla Parsons, S. Štěpánková, Jana Prescimone, A. Habtemariam, Abraha Brabec, Viktor Parkin, A. Sadler, Peter
n3:zamer
n5:AV0Z50040702 n5:MSM6198959216 n5:AV0Z50040507
s:issn
0020-1669
s:numberOfPages
17
n12:organizacniJednotka
15310