This HTML5 document contains 44 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n14http://localhost/temp/predkladatel/
n19http://linked.opendata.cz/resource/domain/vavai/projekt/
n13http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n18http://linked.opendata.cz/ontology/domain/vavai/
n6http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n7http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61989592%3A15310%2F07%3A00005816%21RIV10-MSM-15310___/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n5http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n10http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n15http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n4http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n17http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n12http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F07%3A00005816%21RIV10-MSM-15310___
rdf:type
skos:Concept n18:Vysledek
dcterms:description
Cluster anions of boron are built up on three-center two-electron bonds in contrast to naturally occurring compounds and their synthetic analogs. Methanol works as a solvent and as a competing agent, which advantageously adjusts reasonable strength of their interaction with native CDs in water-organic BGE. The highest methanol concentration preserving chiral discrimination of atropoisomers of individual anions is approximately 35, 55 and 75% v/v for -, - and -CD, respectively. -CD separates anionic 7, 8-nido-dicarbaundecaborate clusters with small exo-skeletal substituents. -CD separates anions of all four tested structural types. The efficiency of separation of a compound with - or -CD is always markedly lower than the separation efficiency at the absence of a CD in BGE. The efficiency of separation of a compound with -CD is always lower than the efficiency of separation of the compound with -CD. -CD was proved to be unsuitable as a chiral selector because in BGEs with -CD, effective mobilities of an Cluster anions of boron are built up on three-center two-electron bonds in contrast to naturally occurring compounds and their synthetic analogs. Methanol works as a solvent and as a competing agent, which advantageously adjusts reasonable strength of their interaction with native CDs in water-organic BGE. The highest methanol concentration preserving chiral discrimination of atropoisomers of individual anions is approximately 35, 55 and 75% v/v for -, - and -CD, respectively. -CD separates anionic 7, 8-nido-dicarbaundecaborate clusters with small exo-skeletal substituents. -CD separates anions of all four tested structural types. The efficiency of separation of a compound with - or -CD is always markedly lower than the separation efficiency at the absence of a CD in BGE. The efficiency of separation of a compound with -CD is always lower than the efficiency of separation of the compound with -CD. -CD was proved to be unsuitable as a chiral selector because in BGEs with -CD, effective mobilities of an
dcterms:title
Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes
skos:prefLabel
Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes Chiral separability of hydrophobic boron cluster anions with native cyclodextrins in water-methanol background electrolytes
skos:notation
RIV/61989592:15310/07:00005816!RIV10-MSM-15310___
n3:aktivita
n4:Z n4:S n4:P
n3:aktivity
P(IAA400310613), S, Z(AV0Z40310501), Z(MSM6198959216)
n3:cisloPeriodika
20
n3:dodaniDat
n12:2010
n3:domaciTvurceVysledku
n13:3217582
n3:druhVysledku
n17:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n7:predkladatel
n3:idSjednocenehoVysledku
413521
n3:idVysledku
RIV/61989592:15310/07:00005816
n3:jazykVysledku
n15:eng
n3:klicovaSlova
Boron cluster compound; CE; Chiral separation; Cyclodextrin; Mixed solvent
n3:klicoveSlovo
n5:Cyclodextrin n5:Mixed%20solvent n5:Chiral%20separation n5:Boron%20cluster%20compound n5:CE
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[675B4466EBCD]
n3:nazevZdroje
Electrophoresis
n3:obor
n16:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:projekt
n19:IAA400310613
n3:rokUplatneniVysledku
n12:2007
n3:svazekPeriodika
28
n3:tvurceVysledku
Horáková, Hana Vespalec, Radim
n3:zamer
n6:MSM6198959216 n6:AV0Z40310501
s:issn
0173-0835
s:numberOfPages
11
n14:organizacniJednotka
15310