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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F07%3A00004705%21RIV08-MSM-15310___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
The mechanism of the Co(II) catalytic electroreduction of water insoluble CoR2 salt in the presence of cysteine (H2L +/-) was developed. CoR2 = cobalt( II) cyclohexylbutyrate is the component of a carbon paste electrode. Electrode surface consecutive reactions are: ( a) fast ( equilibrium) reaction of the CoR2 (H2L +/-)(ads) complex formation, (b) rate-determining reversible reaction of the promoting process of CoR(Ac+) complex formation, (c) rate-determining irreversible reaction of the electroactive CoR(Ac)(H2L +/-)(ads) complex formation with ligand-induced adsorption, and (d) fast irreversible reaction of the CoR(Ac)(H2L +/-)(ads) electroreduction. Reactions ( a, b) connected with CoR2 dissolution and reactions ( c, d) connected with CoR2 electroreduction are catalyzed by H2L +/-)(ads). Regeneration of (H2L +/-)(ads) ( reactions %22b, d%22) and accumulation of atomic Co( 0) ( reaction %22d%22) take place. Experimental data [Sugawara et al., Bioelectrochem Bioenergetics 26: 469, 1991]: The mechanism of the Co(II) catalytic electroreduction of water insoluble CoR2 salt in the presence of cysteine (H2L +/-) was developed. CoR2 = cobalt( II) cyclohexylbutyrate is the component of a carbon paste electrode. Electrode surface consecutive reactions are: ( a) fast ( equilibrium) reaction of the CoR2 (H2L +/-)(ads) complex formation, (b) rate-determining reversible reaction of the promoting process of CoR(Ac+) complex formation, (c) rate-determining irreversible reaction of the electroactive CoR(Ac)(H2L +/-)(ads) complex formation with ligand-induced adsorption, and (d) fast irreversible reaction of the CoR(Ac)(H2L +/-)(ads) electroreduction. Reactions ( a, b) connected with CoR2 dissolution and reactions ( c, d) connected with CoR2 electroreduction are catalyzed by H2L +/-)(ads). Regeneration of (H2L +/-)(ads) ( reactions %22b, d%22) and accumulation of atomic Co( 0) ( reaction %22d%22) take place. Experimental data [Sugawara et al., Bioelectrochem Bioenergetics 26: 469, 1991]: Byl navržen mechanismus elektrokatalytické redukce Co(II) nerozpustné CoR2 soli v přítomnosti cysteinu
dcterms:title
Mechanism of the catalyzed by cysteine electroreduction of the insoluble in water cobalt(II) salt as a component of carbon paste electrode Mechanism of the catalyzed by cysteine electroreduction of the insoluble in water cobalt(II) salt as a component of carbon paste electrode Mechanismus cysteinem katalyzované elektroredukce nerozpustné soli kobaltu jako komponenty uhlíkové pastové elektrody
skos:prefLabel
Mechanismus cysteinem katalyzované elektroredukce nerozpustné soli kobaltu jako komponenty uhlíkové pastové elektrody Mechanism of the catalyzed by cysteine electroreduction of the insoluble in water cobalt(II) salt as a component of carbon paste electrode Mechanism of the catalyzed by cysteine electroreduction of the insoluble in water cobalt(II) salt as a component of carbon paste electrode
skos:notation
RIV/61989592:15310/07:00004705!RIV08-MSM-15310___
n4:strany
841-846
n4:aktivita
n6:Z n6:P
n4:aktivity
P(1M0512), Z(MSM6198959218)
n4:cisloPeriodika
6
n4:dodaniDat
n12:2008
n4:domaciTvurceVysledku
n13:9119922 n13:8419647
n4:druhVysledku
n16:J
n4:duvernostUdaju
n9:S
n4:entitaPredkladatele
n8:predkladatel
n4:idSjednocenehoVysledku
432612
n4:idVysledku
RIV/61989592:15310/07:00004705
n4:jazykVysledku
n18:eng
n4:klicovaSlova
modified carbon paste electrode; Co(II) catalytic electroreduction; cysteine as catalyst; catalysis mechanism; kinetic equations
n4:klicoveSlovo
n5:catalysis%20mechanism n5:kinetic%20equations n5:modified%20carbon%20paste%20electrode n5:Co%28II%29%20catalytic%20electroreduction n5:cysteine%20as%20catalyst
n4:kodStatuVydavatele
US - Spojené státy americké
n4:kontrolniKodProRIV
[708EDBBAF49E]
n4:nazevZdroje
Journal of Solid State Electrochemistry
n4:obor
n15:CF
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
3
n4:projekt
n11:1M0512
n4:rokUplatneniVysledku
n12:2007
n4:svazekPeriodika
11
n4:tvurceVysledku
Hrbáč, Jan Tur'yan, Yakov I. Zelený, Tomáš
n4:zamer
n14:MSM6198959218
s:issn
1432-8488
s:numberOfPages
6
n17:organizacniJednotka
15310