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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F06%3A00005809%21RIV10-MSM-15310___
rdf:type
n8:Vysledek skos:Concept
dcterms:description
Online combination of transient ITP and CZE is employed for the determination of Cd(II), Pb(II), Cu(II), Ni(II), and Zn(II). Acetic acid is used for creating the transient isotachophoretic state. a-Hydroxyisobutyric acid and 4-aminopyridine are used as BGEs for the separation and indirect UV detection. At optimum conditions, the method allows to determine the metals at levels of 40 - 120 mu g/L, about 50 times more sensitive than conventional CZE. In combination with a 20-fold evaporative concentration, the method is suitable for environmental monitoring of the heavy metals in snow samples. Online combination of transient ITP and CZE is employed for the determination of Cd(II), Pb(II), Cu(II), Ni(II), and Zn(II). Acetic acid is used for creating the transient isotachophoretic state. a-Hydroxyisobutyric acid and 4-aminopyridine are used as BGEs for the separation and indirect UV detection. At optimum conditions, the method allows to determine the metals at levels of 40 - 120 mu g/L, about 50 times more sensitive than conventional CZE. In combination with a 20-fold evaporative concentration, the method is suitable for environmental monitoring of the heavy metals in snow samples.
dcterms:title
Determination of some heavy metal cations in molten snow by transient isotachophoresis/capillary zone electrophoresis Determination of some heavy metal cations in molten snow by transient isotachophoresis/capillary zone electrophoresis
skos:prefLabel
Determination of some heavy metal cations in molten snow by transient isotachophoresis/capillary zone electrophoresis Determination of some heavy metal cations in molten snow by transient isotachophoresis/capillary zone electrophoresis
skos:notation
RIV/61989592:15310/06:00005809!RIV10-MSM-15310___
n3:aktivita
n11:S n11:Z
n3:aktivity
S, Z(MSM6198959216)
n3:cisloPeriodika
14
n3:dodaniDat
n5:2010
n3:domaciTvurceVysledku
n16:2465205
n3:druhVysledku
n4:J
n3:duvernostUdaju
n13:S
n3:entitaPredkladatele
n15:predkladatel
n3:idSjednocenehoVysledku
471180
n3:idVysledku
RIV/61989592:15310/06:00005809
n3:jazykVysledku
n6:eng
n3:klicovaSlova
capillary zone electrophoresis; environmental analysis; heavy metals; snow; transient isotachophoresis
n3:klicoveSlovo
n10:capillary%20zone%20electrophoresis n10:heavy%20metals n10:environmental%20analysis n10:snow n10:transient%20isotachophoresis
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[DBFA5C71B782]
n3:nazevZdroje
Journal of Separation Science
n3:obor
n12:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n5:2006
n3:svazekPeriodika
29
n3:tvurceVysledku
Gertsmann, Silke Petr, Jan Frank, Harmut
n3:zamer
n18:MSM6198959216
s:issn
1615-9306
s:numberOfPages
5
n17:organizacniJednotka
15310