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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F06%3A00003364%21RIV10-MSM-15310___
rdf:type
n5:Vysledek skos:Concept
dcterms:description
Chiral analysis is an important task of analytical chemistry. Besides separation techniques, mass spectrometry can be applied in this field. One mass spectrometric approach is based on Cooks' kinetic method. The method was successfully applied in a static system in which the concentration of the analyte as well as the chiral selector solution was constant during the experiment. The application of the kinetic method in dynamic systems (changing concentration of analyte) is presented. Such systems allow the speeding up of the analytical process (flow injection analysis (FIA)) or the use of the kinetic method for chiral detection after liquid chromatographic separation. The influence of the concentration of the components of the chiral selector solution as well as its flow rate on the recognition of enantiomers was evaluated. A new procedure for correction for the differences between ratio of enantiomers in the liquid phase and their observed ratio in the gas phase is also described. A significant Chiral analysis is an important task of analytical chemistry. Besides separation techniques, mass spectrometry can be applied in this field. One mass spectrometric approach is based on Cooks' kinetic method. The method was successfully applied in a static system in which the concentration of the analyte as well as the chiral selector solution was constant during the experiment. The application of the kinetic method in dynamic systems (changing concentration of analyte) is presented. Such systems allow the speeding up of the analytical process (flow injection analysis (FIA)) or the use of the kinetic method for chiral detection after liquid chromatographic separation. The influence of the concentration of the components of the chiral selector solution as well as its flow rate on the recognition of enantiomers was evaluated. A new procedure for correction for the differences between ratio of enantiomers in the liquid phase and their observed ratio in the gas phase is also described. A significant
dcterms:title
Chiral analysis by mass spectrometry using the kinetic method in flow systems Chiral analysis by mass spectrometry using the kinetic method in flow systems
skos:prefLabel
Chiral analysis by mass spectrometry using the kinetic method in flow systems Chiral analysis by mass spectrometry using the kinetic method in flow systems
skos:notation
RIV/61989592:15310/06:00003364!RIV10-MSM-15310___
n3:aktivita
n4:Z
n3:aktivity
Z(MSM6198959216)
n3:cisloPeriodika
4
n3:dodaniDat
n15:2010
n3:domaciTvurceVysledku
n14:8390924 n14:6833446 n14:4316851 n14:6267408 n14:7415540
n3:druhVysledku
n16:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
468589
n3:idVysledku
RIV/61989592:15310/06:00003364
n3:jazykVysledku
n10:eng
n3:klicovaSlova
mass spectrometry; chiral analysis of amino acids; kinetic method; flow injection analysis; HPLC/MS
n3:klicoveSlovo
n8:chiral%20analysis%20of%20amino%20acids n8:flow%20injection%20analysis n8:kinetic%20method n8:mass%20spectrometry n8:HPLC%2FMS
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[20C512100A5F]
n3:nazevZdroje
Journal of Mass Spectrometry
n3:obor
n17:CB
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:rokUplatneniVysledku
n15:2006
n3:svazekPeriodika
41
n3:tvurceVysledku
Bednář, Petr Ševčík, Juraj Fryčák, Petr Lemr, Karel Ranc, Václav
n3:zamer
n12:MSM6198959216
s:issn
1076-5174
s:numberOfPages
8
n9:organizacniJednotka
15310