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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F05%3A00001894%21RIV06-MSM-15310___
rdf:type
n9:Vysledek skos:Concept
dcterms:description
The octanol-water partition coefficients of seven anthocyanins (in neutral form, pH = 7.0) were measured by means of MEKC. A new iterative method for the estimation of migration time of electroosmotic flow (EOF) and micelles in MEKC is presented. This calculation is based on Gauss-Newton linearization of the dependence between migration indices and migration times of a set of suitable standards and the application of an advanced statistical evaluation procedure. The values of partition coefficients obtained with the aid of an iterative process are compared with values obtained on use of EOF and micelle markers. Je diskutován odhad rozdělovacích koeficientů pomocí MEKC. Druhá část je věnována antokyaninům. The octanol-water partition coefficients of seven anthocyanins (in neutral form, pH = 7.0) were measured by means of MEKC. A new iterative method for the estimation of migration time of electroosmotic flow (EOF) and micelles in MEKC is presented. This calculation is based on Gauss-Newton linearization of the dependence between migration indices and migration times of a set of suitable standards and the application of an advanced statistical evaluation procedure. The values of partition coefficients obtained with the aid of an iterative process are compared with values obtained on use of EOF and micelle markers.
dcterms:title
Odhad rozdělovacích koeficientů pomocí MEKC - část 2: antokyaniny Estimation of partition coefficients by MEKC - Part 2: Anthocyanins Estimation of partition coefficients by MEKC - Part 2: Anthocyanins
skos:prefLabel
Odhad rozdělovacích koeficientů pomocí MEKC - část 2: antokyaniny Estimation of partition coefficients by MEKC - Part 2: Anthocyanins Estimation of partition coefficients by MEKC - Part 2: Anthocyanins
skos:notation
RIV/61989592:15310/05:00001894!RIV06-MSM-15310___
n3:strany
1285-1290
n3:aktivita
n6:Z n6:P
n3:aktivity
P(GP203/02/D013), Z(MSM6198959216)
n3:cisloPeriodika
12
n3:dodaniDat
n12:2006
n3:domaciTvurceVysledku
n11:6267408 n11:4316851 n11:8390924 n11:1077074
n3:druhVysledku
n16:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n4:predkladatel
n3:idSjednocenehoVysledku
520561
n3:idVysledku
RIV/61989592:15310/05:00001894
n3:jazykVysledku
n18:eng
n3:klicovaSlova
ELECTROKINETIC CAPILLARY CHROMATOGRAPHY; ATOMIC PHYSICOCHEMICAL PARAMETERS; DIRECTED QUANTITATIVE STRUCTURE; LIQUID-CHROMATOGRAPHY; INDEX; WATER
n3:klicoveSlovo
n8:INDEX n8:DIRECTED%20QUANTITATIVE%20STRUCTURE n8:ATOMIC%20PHYSICOCHEMICAL%20PARAMETERS n8:WATER n8:ELECTROKINETIC%20CAPILLARY%20CHROMATOGRAPHY n8:LIQUID-CHROMATOGRAPHY
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[61AE09FC6C8B]
n3:nazevZdroje
Journal of Separation Science
n3:obor
n14:CB
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
5
n3:projekt
n13:GP203%2F02%2FD013
n3:rokUplatneniVysledku
n12:2005
n3:svazekPeriodika
28
n3:tvurceVysledku
Barták, Petr Ševčík, Juraj Lemr, Karel Bednář, Petr Müller, L.
n3:zamer
n19:MSM6198959216
s:issn
1615-9306
s:numberOfPages
6
n17:organizacniJednotka
15310