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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F04%3A00009886%21RIV10-MSM-15310___
rdf:type
n16:Vysledek skos:Concept
dcterms:description
New nickel, cobalt and copper complexes with benzene-1,2-dithiole (bdt), of general formula R[M(bdt)2]: M = Ni, Co and Cu; R = Me4N, Et4N, Pr4N, Me3PhP, Ph4P have been synthesized and characterized by standard physico-chemical methods (elemental analyses, magnetochemical and conductivity measurements, i.r. and u.v.-vis. spectroscopy). X-ray structural analysis of (MePh3P)[M(bdt)2], M = Ni, Co and Cu, confirms that the MS4 chromophore lies in a slightly distorted square coordination arranagement around the central atom. The three complexes have also been studied by cyclic voltammetry. New nickel, cobalt and copper complexes with benzene-1,2-dithiole (bdt), of general formula R[M(bdt)2]: M = Ni, Co and Cu; R = Me4N, Et4N, Pr4N, Me3PhP, Ph4P have been synthesized and characterized by standard physico-chemical methods (elemental analyses, magnetochemical and conductivity measurements, i.r. and u.v.-vis. spectroscopy). X-ray structural analysis of (MePh3P)[M(bdt)2], M = Ni, Co and Cu, confirms that the MS4 chromophore lies in a slightly distorted square coordination arranagement around the central atom. The three complexes have also been studied by cyclic voltammetry.
dcterms:title
Synthesis, properties and crystal structures of R[M(III)(bdt)2] complexes (M = Ni, Co, Cu) Synthesis, properties and crystal structures of R[M(III)(bdt)2] complexes (M = Ni, Co, Cu)
skos:prefLabel
Synthesis, properties and crystal structures of R[M(III)(bdt)2] complexes (M = Ni, Co, Cu) Synthesis, properties and crystal structures of R[M(III)(bdt)2] complexes (M = Ni, Co, Cu)
skos:notation
RIV/61989592:15310/04:00009886!RIV10-MSM-15310___
n3:aktivita
n17:Z
n3:aktivity
Z(MSM 153100007)
n3:cisloPeriodika
3
n3:dodaniDat
n13:2010
n3:domaciTvurceVysledku
n9:2068079 n9:1000462 n9:5892961
n3:druhVysledku
n10:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n6:predkladatel
n3:idSjednocenehoVysledku
589383
n3:idVysledku
RIV/61989592:15310/04:00009886
n3:jazykVysledku
n7:eng
n3:klicovaSlova
transition metal complexes; coordination compounds; dithiolates
n3:klicoveSlovo
n8:transition%20metal%20complexes n8:coordination%20compounds n8:dithiolates
n3:kodStatuVydavatele
GB - Spojené království Velké Británie a Severního Irska
n3:kontrolniKodProRIV
[6E0D9A530C72]
n3:nazevZdroje
Transition Metal Chemistry
n3:obor
n14:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
7
n3:rokUplatneniVysledku
n13:2004
n3:svazekPeriodika
29
n3:tvurceVysledku
Kameníček, Jiří Mrkvová, Kateřina Šindelář, Zdeněk Žák, Zdirad Nahorska, Monika Kvítek, Libor Mroziński, Jerzy
n3:zamer
n15:MSM%20153100007
s:issn
0340-4285
s:numberOfPages
7
n11:organizacniJednotka
15310