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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F04%3A00002259%21RIV%2F2005%2FMSM%2F153105%2FN
rdf:type
skos:Concept n14:Vysledek
dcterms:description
The Kinetic Method (KM), applied commonly for thermochemical determinations, is used here for sterically-controlled isomeric determination of N- versus C-terminal Arg-containing dipeptide isomers (ArgX versus XArg; where X = His, Leu, Lys, Pro, Ser, Phe, and Tyr). The KM is offered as an alternate approach to direct collision-induced dissociation (CID) procedures. Through formation, isolation, and dissociation of a sterically-encumbered, metalcentered complex with electrospray ionization ion trap mass spectrometry technology, reference dipeptide molecules are screened to quantitatively differentiate a mixture of isomers based on their arrangement about the metal center. Arg-containing dipeptide molecules are chosen because of their contribution in a wide array of protein and peptide functions. Additionally, problems cited previously for evaluation of systems containing Arg residues (due to the incorporation of the guanidinium moiety) by the KM are addressed. The method is shown to be successful for hi The Kinetic Method (KM), applied commonly for thermochemical determinations, is used here for sterically-controlled isomeric determination of N- versus C-terminal Arg-containing dipeptide isomers (ArgX versus XArg; where X = His, Leu, Lys, Pro, Ser, Phe, and Tyr). The KM is offered as an alternate approach to direct collision-induced dissociation (CID) procedures. Through formation, isolation, and dissociation of a sterically-encumbered, metalcentered complex with electrospray ionization ion trap mass spectrometry technology, reference dipeptide molecules are screened to quantitatively differentiate a mixture of isomers based on their arrangement about the metal center. Arg-containing dipeptide molecules are chosen because of their contribution in a wide array of protein and peptide functions. Additionally, problems cited previously for evaluation of systems containing Arg residues (due to the incorporation of the guanidinium moiety) by the KM are addressed. The method is shown to be successful for hi Pro stanovení byla aplikována isomerická diskriminace arginin obsahujících dipeptidů s využitím hmotnostní spektroemtrie s ionizací elektrosprejem a kinetické metody.
dcterms:title
Isomeric discrimination of arginine-containing dipeptides using electrospray ionization-ion trap mass spectrometry and the kinetic method Isomerická diskriminace arginin obsahujících dipeptidů s využitím hmotnostní spektroemtrie s ionizací elektrosprejem a kinetické metody Isomeric discrimination of arginine-containing dipeptides using electrospray ionization-ion trap mass spectrometry and the kinetic method
skos:prefLabel
Isomerická diskriminace arginin obsahujících dipeptidů s využitím hmotnostní spektroemtrie s ionizací elektrosprejem a kinetické metody Isomeric discrimination of arginine-containing dipeptides using electrospray ionization-ion trap mass spectrometry and the kinetic method Isomeric discrimination of arginine-containing dipeptides using electrospray ionization-ion trap mass spectrometry and the kinetic method
skos:notation
RIV/61989592:15310/04:00002259!RIV/2005/MSM/153105/N
n3:strany
840-847
n3:aktivita
n16:Z
n3:aktivity
Z(MSM 153100013)
n3:cisloPeriodika
6
n3:dodaniDat
n13:2005
n3:domaciTvurceVysledku
n6:4316851
n3:druhVysledku
n17:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n5:predkladatel
n3:idSjednocenehoVysledku
569082
n3:idVysledku
RIV/61989592:15310/04:00002259
n3:jazykVysledku
n7:eng
n3:klicovaSlova
GAS-PHASE;THERMOCHEMICAL DETERMINATIONS;PROTON AFFINITIES;AMINO-ACIDS;CHIRAL RECOGNITION;PEPTIDE IONS;COMPLEXES;DIFFERENTIATION;DISSOCIATION;QUANTIFICATION
n3:klicoveSlovo
n8:QUANTIFICATION n8:COMPLEXES n8:PEPTIDE%20IONS n8:DIFFERENTIATION n8:CHIRAL%20RECOGNITION n8:AMINO-ACIDS n8:THERMOCHEMICAL%20DETERMINATIONS n8:PROTON%20AFFINITIES n8:GAS-PHASE n8:DISSOCIATION
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[2D88FFE31DCB]
n3:nazevZdroje
Journal of the American Society for Mass Spectrometry
n3:obor
n18:CB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:rokUplatneniVysledku
n13:2004
n3:svazekPeriodika
15
n3:tvurceVysledku
Lindner, W. Lemr, Karel Schug, K. A.
n3:zamer
n4:MSM%20153100013
s:issn
1044-0305
s:numberOfPages
8
n10:organizacniJednotka
15310