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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F04%3A00002128%21RIV%2F2005%2FMSM%2F153105%2FN
rdf:type
n9:Vysledek skos:Concept
dcterms:description
A simplified quantitative model of chemiluminescence intramicellar sensitization is proposed, based on the analytical solution of Forster's energy transfer function for donor-acceptor pairs residing on micellar spherical surface. To test the usability of the model, the intramicellar sensitization of phthalhydrazide chemiluminescent oxidation by energy transfer to several xanthene as well as non-xanthene dyes has been investigated. The reactions were initiated using three different initiation systems: copper sulphate-hydrogen peroxide system, sodium hypochlorite and hydrogen peroxide-sodium hypochlorite. In this work, we bring an experimental evidence that different transfer mechanisms operate, if phthalhydrazide-sensitized chemiluminescence reactions are initiated by copper sulphate-hydrogen peroxide, sodium hypochlorite or sodium hypochlorite-hydrogen peroxide. Only the latter system is selective enough to oxidize phthalic hydrazide much more rapidly than dyes employed as acceptors. This fact enables A simplified quantitative model of chemiluminescence intramicellar sensitization is proposed, based on the analytical solution of Forster's energy transfer function for donor-acceptor pairs residing on micellar spherical surface. To test the usability of the model, the intramicellar sensitization of phthalhydrazide chemiluminescent oxidation by energy transfer to several xanthene as well as non-xanthene dyes has been investigated. The reactions were initiated using three different initiation systems: copper sulphate-hydrogen peroxide system, sodium hypochlorite and hydrogen peroxide-sodium hypochlorite. In this work, we bring an experimental evidence that different transfer mechanisms operate, if phthalhydrazide-sensitized chemiluminescence reactions are initiated by copper sulphate-hydrogen peroxide, sodium hypochlorite or sodium hypochlorite-hydrogen peroxide. Only the latter system is selective enough to oxidize phthalic hydrazide much more rapidly than dyes employed as acceptors. This fact enables Byla vyšetřována senzitizovaná chemiluminescence v micelárních roztocích obsahujících ftalhydrazid a vybraná barviva.
dcterms:title
Senzitizovaná chemiluminescence v micelárních roztocích obsahujících ftalhydrazid a vybraná barviva Sensitized chemiluminescence in micellar mixtures of phthalhydrazide and selected dyes Sensitized chemiluminescence in micellar mixtures of phthalhydrazide and selected dyes
skos:prefLabel
Sensitized chemiluminescence in micellar mixtures of phthalhydrazide and selected dyes Senzitizovaná chemiluminescence v micelárních roztocích obsahujících ftalhydrazid a vybraná barviva Sensitized chemiluminescence in micellar mixtures of phthalhydrazide and selected dyes
skos:notation
RIV/61989592:15310/04:00002128!RIV/2005/MSM/153105/N
n3:strany
169-175
n3:aktivita
n16:Z
n3:aktivity
Z(MSM 153100007)
n3:cisloPeriodika
2-3
n3:dodaniDat
n10:2005
n3:domaciTvurceVysledku
n6:5136326 n6:8419647 n6:5964423 n6:3373215
n3:druhVysledku
n17:J
n3:duvernostUdaju
n12:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
585890
n3:idVysledku
RIV/61989592:15310/04:00002128
n3:jazykVysledku
n7:eng
n3:klicovaSlova
phthalhydrazide;sensitized chemiluminescence;energy transfer;CTA micelles
n3:klicoveSlovo
n11:energy%20transfer n11:CTA%20micelles n11:phthalhydrazide n11:sensitized%20chemiluminescence
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[91A6A9C9A98A]
n3:nazevZdroje
Journal of Photochemistry and Photobiology, A: Chemistry
n3:obor
n18:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
6
n3:rokUplatneniVysledku
n10:2004
n3:svazekPeriodika
167
n3:tvurceVysledku
Sichertová, Dana Bancířová, Martina Papadopoulos, Kyriakos Hrbáč, Jan Lasovský, Jan Nikokavouras, J.
n3:zamer
n15:MSM%20153100007
s:issn
1010-6030
s:numberOfPages
7
n13:organizacniJednotka
15310