This HTML5 document contains 53 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n6http://localhost/temp/predkladatel/
n8http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n18http://linked.opendata.cz/ontology/domain/vavai/
n16http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61989592%3A15310%2F04%3A00002045%21RIV%2F2005%2FMSM%2F153105%2FN/
n12http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n4http://linked.opendata.cz/ontology/domain/vavai/riv/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n9http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n14http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n13http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n5http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n17http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n11http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F04%3A00002045%21RIV%2F2005%2FMSM%2F153105%2FN
rdf:type
n18:Vysledek skos:Concept
dcterms:description
Intermolecular association and ion-pair formation, respectively, between a cationic chiral selector, viz. o-9-(tert-butylcarbamoyl) quinine (CQN), and the both enantiomers of anionic N-(3,5-dinitrobenzoyl)leucine, (R)-DNB-Leu and (S)-DNB-Leu, were investigated by affinity capillary electrophoresis (ACE). Thus, binding constants of the both diastereomeric ion-pairs, (R) and (S)-DNB-Leu/CQN associates, were determined by different experimental setups and correction of nonlinear effects. A reciprocal setup was employed for the high-affinity (S)-enantiomer, and the experimental mobility data obtained for CQN at variable (S)-DNB-Leu concentrations in the background electrolyte were linearized and evaluated by advanced statistical model. A binding constant of K-S = 125.11 mol(-1) was afforded. The constant for the (R)-enantiomer, which is outside the range suitable for direct affinity CE, was obtained from indirect affinity CE utilizing the separation of the DNB-Leu racemate at a single appropriate CQN conc Intermolecular association and ion-pair formation, respectively, between a cationic chiral selector, viz. o-9-(tert-butylcarbamoyl) quinine (CQN), and the both enantiomers of anionic N-(3,5-dinitrobenzoyl)leucine, (R)-DNB-Leu and (S)-DNB-Leu, were investigated by affinity capillary electrophoresis (ACE). Thus, binding constants of the both diastereomeric ion-pairs, (R) and (S)-DNB-Leu/CQN associates, were determined by different experimental setups and correction of nonlinear effects. A reciprocal setup was employed for the high-affinity (S)-enantiomer, and the experimental mobility data obtained for CQN at variable (S)-DNB-Leu concentrations in the background electrolyte were linearized and evaluated by advanced statistical model. A binding constant of K-S = 125.11 mol(-1) was afforded. The constant for the (R)-enantiomer, which is outside the range suitable for direct affinity CE, was obtained from indirect affinity CE utilizing the separation of the DNB-Leu racemate at a single appropriate CQN conc Byla prováděna pokročilá statistická vyhodnocení konstant stability komplexů z elektroforetických dat II - diastereometrické iontové páry (R,S)-N-(3,5-dinitrobenzoyl)leucinu a terc-butylcarbamoylquininu.
dcterms:title
Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine Pokročilé statistické vyhodnocení konstant stability komplexů z elektroforetických dat II - diastereometrické iontové páry (R,S)-N-(3,5-dinitrobenzoyl)leucinu a terc-butylcarbamoylquininu Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine
skos:prefLabel
Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine Advanced statistical evaluation of the complex formation constants from electrophoretic data II - Diastereomeric ion-pairs of (R,S)-N-(3,5-dinitrobenzoyl)leucine and tert-butylcarbamoylquinine Pokročilé statistické vyhodnocení konstant stability komplexů z elektroforetických dat II - diastereometrické iontové páry (R,S)-N-(3,5-dinitrobenzoyl)leucinu a terc-butylcarbamoylquininu
skos:notation
RIV/61989592:15310/04:00002045!RIV/2005/MSM/153105/N
n4:strany
105-113
n4:aktivita
n13:Z
n4:aktivity
Z(MSM 153100013)
n4:cisloPeriodika
1
n4:dodaniDat
n11:2005
n4:domaciTvurceVysledku
n8:4701321 n8:8390924 n8:1077074 n8:3402568
n4:druhVysledku
n17:J
n4:duvernostUdaju
n14:S
n4:entitaPredkladatele
n16:predkladatel
n4:idSjednocenehoVysledku
553611
n4:idVysledku
RIV/61989592:15310/04:00002045
n4:jazykVysledku
n5:eng
n4:klicovaSlova
statistical theory of experiment;advanced statistical evaluation;binding constants;ion-pair formation constants;affinity capillary electrophoresis;leucine;tert-butyl carbamoyl quinine
n4:klicoveSlovo
n9:leucine n9:affinity%20capillary%20electrophoresis n9:tert-butyl%20carbamoyl%20quinine n9:binding%20constants n9:ion-pair%20formation%20constants n9:advanced%20statistical%20evaluation n9:statistical%20theory%20of%20experiment
n4:kodStatuVydavatele
NL - Nizozemsko
n4:kontrolniKodProRIV
[2A4D592998A6]
n4:nazevZdroje
Analytica Chimica Acta
n4:obor
n15:CB
n4:pocetDomacichTvurcuVysledku
4
n4:pocetTvurcuVysledku
6
n4:rokUplatneniVysledku
n11:2004
n4:svazekPeriodika
506
n4:tvurceVysledku
Stránský, Zdeněk Lindner, W. Barták, Petr Lammerhofer, M. Bednář, Petr Kubáček, Lubomír
n4:zamer
n12:MSM%20153100013
s:issn
0003-2670
s:numberOfPages
9
n6:organizacniJednotka
15310