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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F02%3A00001599%21RIV%2F2003%2FMSM%2F153103%2FN
rdf:type
skos:Concept n18:Vysledek
dcterms:description
Non-sym. substituted Ni(II)dithiocarbamate complexes with NiS2P2 chromophore of compn. [Ni(bziprdtc)(PPh3)2]X, [Ni(bziprdtc)(PPh3)2]BPh4#3H2O (bziprdtc- = benzylisopropyldithiocarbamate, PPh3 = triphenylphosphine, BPh4- = tetraphenylborate, X = ClO4-, PF6-), [Ni(cetdtc)(PPh3)2]X, [Ni(cetdtc)(PPh3)2]PF6, [Ni(cetdtc)(PBut3)2]X (cetdtc- = cyclohexylethyldithiocarbamate, PBut3 = tributylphosphine, X = ClO4-, BPh4-) have been isolated. These complexes have been characterized by elemental anal., IR and UV-VIS spectroscopy, thermal anal., magnetochem. and cond. measurements. X-ray structural anal. of [Ni(bziprdtc)(PPh3)2]ClO4#0.5H2O confirms the NiS2P2 chromophore with a slightly distorted square arrangement around the central atom. Non-sym. substituted Ni(II)dithiocarbamate complexes with NiS2P2 chromophore of compn. [Ni(bziprdtc)(PPh3)2]X, [Ni(bziprdtc)(PPh3)2]BPh4#3H2O (bziprdtc- = benzylisopropyldithiocarbamate, PPh3 = triphenylphosphine, BPh4- = tetraphenylborate, X = ClO4-, PF6-), [Ni(cetdtc)(PPh3)2]X, [Ni(cetdtc)(PPh3)2]PF6, [Ni(cetdtc)(PBut3)2]X (cetdtc- = cyclohexylethyldithiocarbamate, PBut3 = tributylphosphine, X = ClO4-, BPh4-) have been isolated. These complexes have been characterized by elemental anal., IR and UV-VIS spectroscopy, thermal anal., magnetochem. and cond. measurements. X-ray structural anal. of [Ni(bziprdtc)(PPh3)2]ClO4#0.5H2O confirms the NiS2P2 chromophore with a slightly distorted square arrangement around the central atom.
dcterms:title
Non-Symmetrical Nickel(II)dithiocarbamates with NiS2P2-Chromophore Non-Symmetrical Nickel(II)dithiocarbamates with NiS2P2-Chromophore
skos:prefLabel
Non-Symmetrical Nickel(II)dithiocarbamates with NiS2P2-Chromophore Non-Symmetrical Nickel(II)dithiocarbamates with NiS2P2-Chromophore
skos:notation
RIV/61989592:15310/02:00001599!RIV/2003/MSM/153103/N
n4:strany
1545-1551
n4:aktivita
n7:Z
n4:aktivity
Z(MSM 153100007)
n4:cisloPeriodika
11
n4:dodaniDat
n11:2003
n4:domaciTvurceVysledku
n5:8392013 n5:1000462 n5:2068079
n4:druhVysledku
n12:J
n4:duvernostUdaju
n9:S
n4:entitaPredkladatele
n17:predkladatel
n4:idSjednocenehoVysledku
655819
n4:idVysledku
RIV/61989592:15310/02:00001599
n4:jazykVysledku
n16:eng
n4:klicovaSlova
nickel II complexes; dithiocarbamates; NiS2P2 chromophore
n4:klicoveSlovo
n6:NiS2P2%20chromophore n6:nickel%20II%20complexes n6:dithiocarbamates
n4:kodStatuVydavatele
PL - Polská republika
n4:kontrolniKodProRIV
[684C97562400]
n4:nazevZdroje
Polish Journal of Chemistry
n4:obor
n8:CA
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
6
n4:pocetUcastnikuAkce
0
n4:pocetZahranicnichUcastnikuAkce
0
n4:rokUplatneniVysledku
n11:2002
n4:svazekPeriodika
76
n4:tvurceVysledku
Kameníček, Jiří Žák, Zdirad Pastorek, Richard Husárek, Josef Pavlíček, Marek Šindelář, Zdeněk
n4:zamer
n14:MSM%20153100007
s:issn
0137-5083
s:numberOfPages
7
n15:organizacniJednotka
15310