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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F02%3A00001531%21RIV%2F2003%2FMSM%2F153103%2FN
rdf:type
n12:Vysledek skos:Concept
dcterms:description
The complex compounds of the formula (R)[Ni-III(tdt)(2)], R = Met(4)N (I), Et4N (II), Pr4N (III), MePh3P (IV), Ph4P (V); tdt = 1-toluene-3,4-dithiole have been synthesized. The crystal structures of the compounds III and IV were determined by X-rays studies. Bond valence as a function of inter-nuclear distance for Ni-S bonds was estimated. On the basis of physico-chemical measurements and bond-valence sum model, the formal oxidation state III of Ni atoms for both structures was proposed. The complex compounds of the formula (R)[Ni-III(tdt)(2)], R = Met(4)N (I), Et4N (II), Pr4N (III), MePh3P (IV), Ph4P (V); tdt = 1-toluene-3,4-dithiole have been synthesized. The crystal structures of the compounds III and IV were determined by X-rays studies. Bond valence as a function of inter-nuclear distance for Ni-S bonds was estimated. On the basis of physico-chemical measurements and bond-valence sum model, the formal oxidation state III of Ni atoms for both structures was proposed.
dcterms:title
Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom
skos:prefLabel
Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom Syntheses and structure of Ni(III) complexes with 1-toluene 3,4-dithiole. Bond-valence approach to the oxidation state of the central atom
skos:notation
RIV/61989592:15310/02:00001531!RIV/2003/MSM/153103/N
n3:strany
483-490
n3:aktivita
n5:Z
n3:aktivity
Z(MSM 153100007)
n3:cisloPeriodika
4
n3:dodaniDat
n8:2003
n3:domaciTvurceVysledku
n9:2068079
n3:druhVysledku
n15:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
666092
n3:idVysledku
RIV/61989592:15310/02:00001531
n3:jazykVysledku
n7:eng
n3:klicovaSlova
nickel(III)dithiolene complexes; crystal structure; synthesis; physico-chemical measurements; bond valences
n3:klicoveSlovo
n4:nickel%28III%29dithiolene%20complexes n4:synthesis n4:crystal%20structure n4:physico-chemical%20measurements n4:bond%20valences
n3:kodStatuVydavatele
PL - Polská republika
n3:kontrolniKodProRIV
[62C590BDBAF2]
n3:nazevZdroje
Polish Journal of Chemistry
n3:obor
n10:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:rokUplatneniVysledku
n8:2002
n3:svazekPeriodika
76
n3:tvurceVysledku
Žák, Zdirad Kameníček, Jiří Valach, Fedor Kratochvil, Bohumil
n3:zamer
n17:MSM%20153100007
s:issn
0137-5083
s:numberOfPages
8
n18:organizacniJednotka
15310