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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F02%3A00001529%21RIV%2F2003%2FMSM%2F153103%2FN
rdf:type
skos:Concept n15:Vysledek
dcterms:description
The new complex compounds of composition [Ni(en)2(mnt)] (I), [Ni(1,2-dap)2 (mnt)].H2O (II), [Ni(n-phen)(mnt)] (III), [Ni2(4,4#-bpy)4(mnt)2Cl(H2O)2].2H2O (IV), [Ni(dpp)(mnt)].H2O (V); [Co(phen)(mnt)].H2O (VI), [Co(dppe)(mnt)].2H2O (VII) and (Me3PhN)2[Ni(mnt)2] (VIII) (en = ethylenediamine, 1,2-dap = 1,2-diaminopropane, n-phen = 5-nitro-1,10-phenanthroline, bpy = bipyridine, mnt2# = maleonitriledithiolate, dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino) propane, Me3PhN+ = trimethylphenylammonium) have been synthesized and studied by common physico-chemical measurements. For compound VIII, the X-ray structure was solved, which confirms the nearly square coordination around the central atom in the NiS4 chromophore. The new complex compounds of composition [Ni(en)2(mnt)] (I), [Ni(1,2-dap)2 (mnt)].H2O (II), [Ni(n-phen)(mnt)] (III), [Ni2(4,4#-bpy)4(mnt)2Cl(H2O)2].2H2O (IV), [Ni(dpp)(mnt)].H2O (V); [Co(phen)(mnt)].H2O (VI), [Co(dppe)(mnt)].2H2O (VII) and (Me3PhN)2[Ni(mnt)2] (VIII) (en = ethylenediamine, 1,2-dap = 1,2-diaminopropane, n-phen = 5-nitro-1,10-phenanthroline, bpy = bipyridine, mnt2# = maleonitriledithiolate, dppe = 1,2-bis(diphenylphosphino)ethane, dppp = 1,3-bis(diphenylphosphino) propane, Me3PhN+ = trimethylphenylammonium) have been synthesized and studied by common physico-chemical measurements. For compound VIII, the X-ray structure was solved, which confirms the nearly square coordination around the central atom in the NiS4 chromophore.
dcterms:title
COBALT AND NICKEL COMPLEXES WITH MALEONITRILEDITHIOLATE AND SELECTED N,P-LIGANDS COBALT AND NICKEL COMPLEXES WITH MALEONITRILEDITHIOLATE AND SELECTED N,P-LIGANDS
skos:prefLabel
COBALT AND NICKEL COMPLEXES WITH MALEONITRILEDITHIOLATE AND SELECTED N,P-LIGANDS COBALT AND NICKEL COMPLEXES WITH MALEONITRILEDITHIOLATE AND SELECTED N,P-LIGANDS
skos:notation
RIV/61989592:15310/02:00001529!RIV/2003/MSM/153103/N
n3:strany
17-25
n3:aktivita
n11:Z
n3:aktivity
Z(MSM 153100007)
n3:cisloPeriodika
N
n3:dodaniDat
n8:2003
n3:domaciTvurceVysledku
n17:2068079
n3:druhVysledku
n14:J
n3:duvernostUdaju
n7:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
641095
n3:idVysledku
RIV/61989592:15310/02:00001529
n3:jazykVysledku
n16:eng
n3:klicovaSlova
Cobalt(II); Nickel(II) maleonitriledithiolates; synthesis; X-ray structure; physico- chemical study.
n3:klicoveSlovo
n10:synthesis n10:Cobalt%28II%29 n10:physico-%20chemical%20study. n10:X-ray%20structure n10:Nickel%28II%29%20maleonitriledithiolates
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[12A1EAA350D4]
n3:nazevZdroje
Acta Universitatis Palackianae Olomucensis, Facultas Rerum Naturalium, Chemica
n3:obor
n5:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:rokUplatneniVysledku
n8:2002
n3:svazekPeriodika
41
n3:tvurceVysledku
Solichová, Petra Mrkvová, Kateřina Kameníček, Jiří
n3:zamer
n6:MSM%20153100007
s:issn
0232-0061
s:numberOfPages
9
n18:organizacniJednotka
15310