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Statements

Subject Item
n2:RIV%2F61989592%3A15310%2F01%3A00001648%21RIV%2F2003%2FMSM%2F153103%2FN
rdf:type
skos:Concept n15:Vysledek
dcterms:description
The novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN) Cu(ept)](n)(.)4nH(2)O (ept = N-(2-aminoethyl)-propane-1,3 diamine) was obtained by the reaction of Cu(ClO4)(2)(.)6H(2)O with N-(2-aminoethyl)propane-1,3-diamine and Na 2[Fe(CN)(5)NO](.)2H(2)O in water. This compound was characterized by IR, UV-VIS and EPR spectroscopies and magnetic measurement. Single-crystal X-ray structure analysis revealed that the title complex has a one-dimensional polymeric structure containing hexacoordinate iron(II) with five cyanide ligands (two of them, in trans position, bridging) and one nitrosyl group, and pentacoordinate copper(II) with N-(2 aminoethyl)propane-1,3-diamine and two sites occupied by bridging cyanide ligands. Magnetic investigation revealed a very weak anti ferromagnetic interaction between the copper atoms (superexchange interaction parameter J = -1.7(1) cm(-1); H = -JS(i)S(i+1)) within the chain through the diamagnetic [Fe(CN)(5)NO](2-) ions. The novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN) Cu(ept)](n)(.)4nH(2)O (ept = N-(2-aminoethyl)-propane-1,3 diamine) was obtained by the reaction of Cu(ClO4)(2)(.)6H(2)O with N-(2-aminoethyl)propane-1,3-diamine and Na 2[Fe(CN)(5)NO](.)2H(2)O in water. This compound was characterized by IR, UV-VIS and EPR spectroscopies and magnetic measurement. Single-crystal X-ray structure analysis revealed that the title complex has a one-dimensional polymeric structure containing hexacoordinate iron(II) with five cyanide ligands (two of them, in trans position, bridging) and one nitrosyl group, and pentacoordinate copper(II) with N-(2 aminoethyl)propane-1,3-diamine and two sites occupied by bridging cyanide ligands. Magnetic investigation revealed a very weak anti ferromagnetic interaction between the copper atoms (superexchange interaction parameter J = -1.7(1) cm(-1); H = -JS(i)S(i+1)) within the chain through the diamagnetic [Fe(CN)(5)NO](2-) ions.
dcterms:title
Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine)
skos:prefLabel
Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine) Synthesis, crystal structure and magnetic properties of novel complex [mu-(NC)-Fe(CN)(3)(NO)-mu-(CN)-Cu(ept)](n)center dot 4nH(2)O (ept = N-(2-aminoethyl)propane-1,3-diamine)
skos:notation
RIV/61989592:15310/01:00001648!RIV/2003/MSM/153103/N
n4:strany
1490-1498
n4:aktivita
n7:Z
n4:aktivity
Z(MSM 153100007)
n4:cisloPeriodika
10
n4:dodaniDat
n9:2003
n4:domaciTvurceVysledku
n6:2395185 n6:2068079
n4:druhVysledku
n10:J
n4:duvernostUdaju
n17:S
n4:entitaPredkladatele
n18:predkladatel
n4:idSjednocenehoVysledku
698113
n4:idVysledku
RIV/61989592:15310/01:00001648
n4:jazykVysledku
n12:eng
n4:klicovaSlova
copper(II); iron(II); cyanide-bridged complexes; diamines; nitroprussides; cyanides; magnetic properties; crystal structure
n4:klicoveSlovo
n5:iron%28II%29 n5:crystal%20structure n5:cyanides n5:nitroprussides n5:diamines n5:copper%28II%29 n5:cyanide-bridged%20complexes n5:magnetic%20properties
n4:kodStatuVydavatele
CZ - Česká republika
n4:kontrolniKodProRIV
[4CC4BE564613]
n4:nazevZdroje
Collection of Czechoslovak Chemical Communications
n4:obor
n11:CA
n4:pocetDomacichTvurcuVysledku
2
n4:pocetTvurcuVysledku
4
n4:pocetUcastnikuAkce
0
n4:pocetZahranicnichUcastnikuAkce
0
n4:rokUplatneniVysledku
n9:2001
n4:svazekPeriodika
66
n4:tvurceVysledku
Smékal, Zdeněk Svoboda, Ingrid Escuer, Albert Kameníček, Jiří
n4:zamer
n16:MSM%20153100007
s:issn
0010-0765
s:numberOfPages
9
n13:organizacniJednotka
15310