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Statements

Subject Item
n2:RIV%2F61989100%3A27710%2F14%3A86091527%21RIV15-MSM-27710___
rdf:type
skos:Concept n19:Vysledek
dcterms:description
ZnS nanoparticles stabilized by cetyltrimethylammonium bromide were deposited on montmorillonite forming the ZnS-MMT nanocomposite. The nanocomposite was characterized by UV-Vis DRS, SEM-EDAX, FTIR, XRD and nitrogen physisorption and tested for N2O photocatalytic decomposition in an annular batch reactor illuminated with an 8 W Hg lamp (254 nm wavelength). Photolysis of N2O was tested at the same conditions. The N2O conversion in inert gas was 79 % after 24 hours of illumination and was atributed to the simultaneous N2O photocatalytic and photochemical decomposition. The presence of water vapor inhibited photocatalytic reaction pathway while N2O photolysis was improved. Photocatalytic performance was higher with catalyst in fluidized bed than in fixed bed. The reason is that both mass and photon transfer to the photocatalyst was maximized. Better results were obtained with Zn-MMT compared to Evonic P25 catalyst ZnS nanoparticles stabilized by cetyltrimethylammonium bromide were deposited on montmorillonite forming the ZnS-MMT nanocomposite. The nanocomposite was characterized by UV-Vis DRS, SEM-EDAX, FTIR, XRD and nitrogen physisorption and tested for N2O photocatalytic decomposition in an annular batch reactor illuminated with an 8 W Hg lamp (254 nm wavelength). Photolysis of N2O was tested at the same conditions. The N2O conversion in inert gas was 79 % after 24 hours of illumination and was atributed to the simultaneous N2O photocatalytic and photochemical decomposition. The presence of water vapor inhibited photocatalytic reaction pathway while N2O photolysis was improved. Photocatalytic performance was higher with catalyst in fluidized bed than in fixed bed. The reason is that both mass and photon transfer to the photocatalyst was maximized. Better results were obtained with Zn-MMT compared to Evonic P25 catalyst
dcterms:title
Photocatalytic and photochemical decomposition of N2O on ZnS-MMT catalyst Photocatalytic and photochemical decomposition of N2O on ZnS-MMT catalyst
skos:prefLabel
Photocatalytic and photochemical decomposition of N2O on ZnS-MMT catalyst Photocatalytic and photochemical decomposition of N2O on ZnS-MMT catalyst
skos:notation
RIV/61989100:27710/14:86091527!RIV15-MSM-27710___
n3:aktivita
n9:S n9:P
n3:aktivity
P(ED2.1.00/03.0069), P(ED2.1.00/03.0100), P(GAP107/11/1918), S
n3:cisloPeriodika
July
n3:dodaniDat
n7:2015
n3:domaciTvurceVysledku
n15:5169348 n15:3453928 n15:3750396 n15:1874365
n3:druhVysledku
n4:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
36469
n3:idVysledku
RIV/61989100:27710/14:86091527
n3:jazykVysledku
n17:eng
n3:klicovaSlova
N2O, Photocatalysis, Photolysis, Decomposition, ZnS, Montmorillonite
n3:klicoveSlovo
n8:ZnS n8:Montmorillonite n8:N2O n8:Decomposition n8:Photolysis n8:Photocatalysis
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[F81FB5B4759D]
n3:nazevZdroje
Catalysis Today
n3:obor
n12:CF
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
5
n3:projekt
n18:GAP107%2F11%2F1918 n18:ED2.1.00%2F03.0069 n18:ED2.1.00%2F03.0100
n3:rokUplatneniVysledku
n7:2014
n3:svazekPeriodika
230
n3:tvurceVysledku
Kočí, Kamila Reli, Martin Obalová, Lucie Praus, Petr Šihor, Marcel
n3:wos
000333800300011
s:issn
0920-5861
s:numberOfPages
6
n10:doi
10.1016/j.cattod.2013.09.047
n13:organizacniJednotka
27710