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Statements

Subject Item
n2:RIV%2F61989100%3A27640%2F04%3A00022335%21RIV10-GA0-27640___
rdf:type
n18:Vysledek skos:Concept
dcterms:description
The surface and interlayer structure of rhodamine B (RhB) montmorillonite for various guest concentrations has been studied using a combination of X-ray powder diffraction and molecular modeling (molecular mechanics and molecular dynamics) in the Cerius2 modeling environment. The joint effect of surface and interlayer structure on the fluorescence spectrum has been observed and discussed in relation to the position and orientation of RhB+ cations with respect to the silicate layer. Structural analysis showed that the surface and interlayer structures are different as to the arrangement of RhB+ cations, and both of them strongly depend on the guest concentration in the intercalation solution and on the method of preparation. The repeated intercalation of montmorillonite by rhodamine B used in the present work allowed obtaining RhB montmorillonite in the maximum degree of ion exchange for every sample. The surface and interlayer structure of rhodamine B (RhB) montmorillonite for various guest concentrations has been studied using a combination of X-ray powder diffraction and molecular modeling (molecular mechanics and molecular dynamics) in the Cerius2 modeling environment. The joint effect of surface and interlayer structure on the fluorescence spectrum has been observed and discussed in relation to the position and orientation of RhB+ cations with respect to the silicate layer. Structural analysis showed that the surface and interlayer structures are different as to the arrangement of RhB+ cations, and both of them strongly depend on the guest concentration in the intercalation solution and on the method of preparation. The repeated intercalation of montmorillonite by rhodamine B used in the present work allowed obtaining RhB montmorillonite in the maximum degree of ion exchange for every sample.
dcterms:title
Effect of surface and interlayer structure on the fluorescence of rhodamine B-montmorillonite: modeling and experiment Effect of surface and interlayer structure on the fluorescence of rhodamine B-montmorillonite: modeling and experiment
skos:prefLabel
Effect of surface and interlayer structure on the fluorescence of rhodamine B-montmorillonite: modeling and experiment Effect of surface and interlayer structure on the fluorescence of rhodamine B-montmorillonite: modeling and experiment
skos:notation
RIV/61989100:27640/04:00022335!RIV10-GA0-27640___
n3:aktivita
n13:P
n3:aktivity
P(GA205/02/0941)
n3:cisloPeriodika
1
n3:dodaniDat
n12:2010
n3:domaciTvurceVysledku
n9:4296729 n9:2173220 n9:3238318 n9:6609147
n3:druhVysledku
n11:J
n3:duvernostUdaju
n17:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
562043
n3:idVysledku
RIV/61989100:27640/04:00022335
n3:jazykVysledku
n8:eng
n3:klicovaSlova
Surface structure; Interlayer structure; Rhodamine B?montmorillonite; Molecular modeling; Fluorescence of rhodamine B
n3:klicoveSlovo
n4:Interlayer%20structure n4:Fluorescence%20of%20rhodamine%20B n4:Surface%20structure n4:Rhodamine%20B%3Fmontmorillonite n4:Molecular%20modeling
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[459C13FBF13C]
n3:nazevZdroje
Journal of Colloid and Interface Science
n3:obor
n6:JI
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
6
n3:projekt
n10:GA205%2F02%2F0941
n3:rokUplatneniVysledku
n12:2004
n3:svazekPeriodika
277
n3:tvurceVysledku
Pospíšil, M. Weiss, Zdeněk Klika, Zdeněk Malý, Petr Čapková, Pavla Weissmannová, Helena
s:issn
0021-9797
s:numberOfPages
10
n15:organizacniJednotka
27640