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Statements

Subject Item
n2:RIV%2F61989100%3A27640%2F00%3A00012242%21RIV%2F2001%2FMSM%2F276401%2FN
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Molecular mechanics simulations, combined with X-ray powder diffraction and infrared spectroscopy, have been used in structure analysis of montmorillonite and beidelite intercalated with tetramethylammonium cations. A complex structure analysis providedus with the detailed structure model, including characterization of the disorder, the total sublimation energy and a charge distribution in the structure of intercalates. The calculated basal spacing (14.36 A for TMA-montmorillonite and 14.12 A for TMA- beidelite) are in good agreement with the experimental values (14.31 A for TMA-montmorillonite and 14.15 A for TMA-beidelite). Both intercalated structures exhibit positional and orientational disorder in the arrangement of TMA cations, and consequently disorder in layer stacking. The most significant difference between TMA-montmorillonite and TMA-beidelite is in the charge distribution on the TMA cations and silicate layers. Molecular mechanics simulations, combined with X-ray powder diffraction and infrared spectroscopy, have been used in structure analysis of montmorillonite and beidelite intercalated with tetramethylammonium cations. A complex structure analysis providedus with the detailed structure model, including characterization of the disorder, the total sublimation energy and a charge distribution in the structure of intercalates. The calculated basal spacing (14.36 A for TMA-montmorillonite and 14.12 A for TMA- beidelite) are in good agreement with the experimental values (14.31 A for TMA-montmorillonite and 14.15 A for TMA-beidelite). Both intercalated structures exhibit positional and orientational disorder in the arrangement of TMA cations, and consequently disorder in layer stacking. The most significant difference between TMA-montmorillonite and TMA-beidelite is in the charge distribution on the TMA cations and silicate layers.
dcterms:title
Montmorillonite and Baidelite Intercalated with Tetramethylammonium Cations. Montmorillonite and Baidelite Intercalated with Tetramethylammonium Cations.
skos:prefLabel
Montmorillonite and Baidelite Intercalated with Tetramethylammonium Cations. Montmorillonite and Baidelite Intercalated with Tetramethylammonium Cations.
skos:notation
RIV/61989100:27640/00:00012242!RIV/2001/MSM/276401/N
n3:strany
600
n3:aktivita
n7:Z n7:P
n3:aktivity
P(GA205/99/0185), Z(MSM 279000017)
n3:cisloPeriodika
6
n3:dodaniDat
n4:2001
n3:domaciTvurceVysledku
Weiss, Zdeněk
n3:druhVysledku
n9:J
n3:duvernostUdaju
n8:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
718092
n3:idVysledku
RIV/61989100:27640/00:00012242
n3:jazykVysledku
n6:eng
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[DF850343E4D1]
n3:nazevZdroje
Journal Molecular Modeling
n3:obor
n14:DB
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
6
n3:projekt
n17:GA205%2F99%2F0185
n3:rokUplatneniVysledku
n4:2000
n3:svazekPeriodika
99
n3:tvurceVysledku
Čapková, Pavla Weiss, Zdeněk
n3:zamer
n13:MSM%20279000017
s:issn
0948-5023
s:numberOfPages
8
n15:organizacniJednotka
27640