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Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F13%3A00391498%21RIV14-MSM-61389013
rdf:type
skos:Concept n8:Vysledek
dcterms:description
N-(2-Hydroxypropyl)methacrylamide polymer precursors (pHPMA) with very narrow distribution of molecular weights and polymer chain terminating in a single reactive group have big potential in the synthesis of various polymer drug and gene delivery systems. This paper shows that pHPMA can be prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization; the pHPMAs prepared by RAFT polymerization conducted to high conversions contained at the α-end of the polymer chain a single functional group originated from both, the chain transfer agent (CTA) and initiator (INI) in ratio depending on polymerization conditions. The well-defined monofunctional pHPMAs with narrow molecular weight distribution and with single reactive group situated at the α-polymer chain end can be prepared in one step by RAFT polymerization initiated by the tailor-made CTA and INI, both containing the same functional group in their structure. Synthesis of pHPMAs terminating in various reactive groups (azide, propargyl, thiazolidin-2-thione, amino, hydrazide) was also described. N-(2-Hydroxypropyl)methacrylamide polymer precursors (pHPMA) with very narrow distribution of molecular weights and polymer chain terminating in a single reactive group have big potential in the synthesis of various polymer drug and gene delivery systems. This paper shows that pHPMA can be prepared by reversible addition-fragmentation chain transfer (RAFT) polymerization; the pHPMAs prepared by RAFT polymerization conducted to high conversions contained at the α-end of the polymer chain a single functional group originated from both, the chain transfer agent (CTA) and initiator (INI) in ratio depending on polymerization conditions. The well-defined monofunctional pHPMAs with narrow molecular weight distribution and with single reactive group situated at the α-polymer chain end can be prepared in one step by RAFT polymerization initiated by the tailor-made CTA and INI, both containing the same functional group in their structure. Synthesis of pHPMAs terminating in various reactive groups (azide, propargyl, thiazolidin-2-thione, amino, hydrazide) was also described.
dcterms:title
Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization
skos:prefLabel
Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization Synthesis of well-defined semitelechelic poly[N-(2-hydroxypropyl)methacrylamide] polymers with functional group at the .alpha.-end of the polymer chain by RAFT polymerization
skos:notation
RIV/61389013:_____/13:00391498!RIV14-MSM-61389013
n8:predkladatel
n9:ico%3A61389013
n3:aktivita
n16:I n16:P
n3:aktivity
I, P(EE2.3.30.0029), P(GAP301/12/1254)
n3:cisloPeriodika
6
n3:dodaniDat
n10:2014
n3:domaciTvurceVysledku
n6:9442286 n6:4763173 n6:8642710 n6:3027368 n6:8890390
n3:druhVysledku
n15:J
n3:duvernostUdaju
n14:S
n3:entitaPredkladatele
n19:predkladatel
n3:idSjednocenehoVysledku
109558
n3:idVysledku
RIV/61389013:_____/13:00391498
n3:jazykVysledku
n17:eng
n3:klicovaSlova
RAFT polymerization; N-(2-hydroxypropyl)methacrylamide; semitelechelic polymers
n3:klicoveSlovo
n12:RAFT%20polymerization n12:semitelechelic%20polymers n12:N-%282-hydroxypropyl%29methacrylamide
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[25D627792AE1]
n3:nazevZdroje
Macromolecules
n3:obor
n18:CD
n3:pocetDomacichTvurcuVysledku
5
n3:pocetTvurcuVysledku
5
n3:projekt
n5:GAP301%2F12%2F1254 n5:EE2.3.30.0029
n3:rokUplatneniVysledku
n10:2013
n3:svazekPeriodika
46
n3:tvurceVysledku
Ulbrich, Karel Šubr, Vladimír Etrych, Tomáš Kostka, Libor Strohalm, Jiří
n3:wos
000316847500007
s:issn
0024-9297
s:numberOfPages
9
n13:doi
10.1021/ma400042u