This HTML5 document contains 60 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n11http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n9http://linked.opendata.cz/resource/domain/vavai/projekt/
n19http://linked.opendata.cz/resource/domain/vavai/subjekt/
n10http://linked.opendata.cz/ontology/domain/vavai/
n5http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n7http://bibframe.org/vocab/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n13http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61389013%3A_____%2F11%3A00364282%21RIV12-AV0-61389013/
n8http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n16http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n18http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n4http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n20http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n17http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n15http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F11%3A00364282%21RIV12-AV0-61389013
rdf:type
n10:Vysledek skos:Concept
dcterms:description
Cellulose-based macroinitiators with predetermined number of initiation sites were synthesized by acylation of microcrystalline cellulose AVICEL PH-101 with 2-bromoisobutyryl bromide under homogeneous reaction conditions in the DMAc/LiCl solvent system. The influence of different methods of cellulose activation on the acylation efficiency and reproducibility was investigated. A new activation protocol, based on solvent exchange to 1,4-dioxane, was introduced. Prepared macroinitiators were used for grafting with styrene and MMA using optimized ATRP reaction conditions to achieve well-controlled polymerizations with high initiation efficiency. In addition, SET LRP technique employing Cu(0) as the catalyst was used for the first time to prepare cellulose-graft-polystyrene and cellulose-graft-poly(MMA) copolymers in a homogeneous phase. Moreover, some of the prepared copolymers were characterized by static and dynamic light scattering, and microscopic techniques. Cellulose-based macroinitiators with predetermined number of initiation sites were synthesized by acylation of microcrystalline cellulose AVICEL PH-101 with 2-bromoisobutyryl bromide under homogeneous reaction conditions in the DMAc/LiCl solvent system. The influence of different methods of cellulose activation on the acylation efficiency and reproducibility was investigated. A new activation protocol, based on solvent exchange to 1,4-dioxane, was introduced. Prepared macroinitiators were used for grafting with styrene and MMA using optimized ATRP reaction conditions to achieve well-controlled polymerizations with high initiation efficiency. In addition, SET LRP technique employing Cu(0) as the catalyst was used for the first time to prepare cellulose-graft-polystyrene and cellulose-graft-poly(MMA) copolymers in a homogeneous phase. Moreover, some of the prepared copolymers were characterized by static and dynamic light scattering, and microscopic techniques.
dcterms:title
Cellulose-based graft copolymers with controlled architecture prepared in a homogeneous phase Cellulose-based graft copolymers with controlled architecture prepared in a homogeneous phase
skos:prefLabel
Cellulose-based graft copolymers with controlled architecture prepared in a homogeneous phase Cellulose-based graft copolymers with controlled architecture prepared in a homogeneous phase
skos:notation
RIV/61389013:_____/11:00364282!RIV12-AV0-61389013
n10:predkladatel
n19:ico%3A61389013
n3:aktivita
n18:Z n18:P
n3:aktivity
P(GA106/09/1348), P(GAP208/10/0353), P(IAA401110702), Z(AV0Z40500505), Z(MSM0021620857)
n3:cisloPeriodika
20
n3:dodaniDat
n15:2012
n3:domaciTvurceVysledku
n11:5617502 n11:5184355 n11:4252454 n11:5574978 n11:1534645 n11:1518755 n11:5079977 n11:3152413
n3:druhVysledku
n20:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n13:predkladatel
n3:idSjednocenehoVysledku
189390
n3:idVysledku
RIV/61389013:_____/11:00364282
n3:jazykVysledku
n4:eng
n3:klicovaSlova
atom transfer radical polymerization (ATRP); cellulose; graft copolymers
n3:klicoveSlovo
n8:cellulose n8:atom%20transfer%20radical%20polymerization%20%28ATRP%29 n8:graft%20copolymers
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[12A9A44AE823]
n3:nazevZdroje
Journal of Polymer Science. Part A - Polymer Chemistry
n3:obor
n17:JI
n3:pocetDomacichTvurcuVysledku
8
n3:pocetTvurcuVysledku
10
n3:projekt
n9:IAA401110702 n9:GAP208%2F10%2F0353 n9:GA106%2F09%2F1348
n3:rokUplatneniVysledku
n15:2011
n3:svazekPeriodika
49
n3:tvurceVysledku
Dybal, Jiří Vlček, Petr Látalová, Petra Štěpánek, M. Kříž, Jaroslav Čadová, Eva Šlouf, Miroslav Uchman, M. Raus, Vladimír Netopilík, Miloš
n3:wos
000295714800007
n3:zamer
n5:MSM0021620857 n5:AV0Z40500505
s:issn
0887-624X
s:numberOfPages
15
n7:doi
10.1002/pola.24876