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Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F10%3A00343972%21RIV11-AV0-61389013
rdf:type
n7:Vysledek skos:Concept
dcterms:description
Formation and transport of polarons in poly[methyl(phenyl) silylene]is discussed. Analytical theory based on the effective medium approach is used to explain the electric field dependence of charge carrier mobility. The obtained value of the polaron binding energy is about 0.29 eV. This result is in agreement with quantum chemical calculations based on the B3LYP method. Charge carrier transport can be described by a small polaron movement in the presence of an energetic disorder. Polaron binding energy represents significant part of the activation energy of the charge mobility. Formation and transport of polarons in poly[methyl(phenyl) silylene]is discussed. Analytical theory based on the effective medium approach is used to explain the electric field dependence of charge carrier mobility. The obtained value of the polaron binding energy is about 0.29 eV. This result is in agreement with quantum chemical calculations based on the B3LYP method. Charge carrier transport can be described by a small polaron movement in the presence of an energetic disorder. Polaron binding energy represents significant part of the activation energy of the charge mobility.
dcterms:title
Feature of polaronic charge carriers in polysilanes: Experimental and theoretical approach Feature of polaronic charge carriers in polysilanes: Experimental and theoretical approach
skos:prefLabel
Feature of polaronic charge carriers in polysilanes: Experimental and theoretical approach Feature of polaronic charge carriers in polysilanes: Experimental and theoretical approach
skos:notation
RIV/61389013:_____/10:00343972!RIV11-AV0-61389013
n3:aktivita
n11:Z n11:P
n3:aktivity
P(IAA100100622), P(KAN400720701), Z(AV0Z40500505)
n3:cisloPeriodika
-
n3:dodaniDat
n13:2011
n3:domaciTvurceVysledku
Kochalska, Anna n15:5801737 n15:8859108
n3:druhVysledku
n5:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n14:predkladatel
n3:idSjednocenehoVysledku
258916
n3:idVysledku
RIV/61389013:_____/10:00343972
n3:jazykVysledku
n17:eng
n3:klicovaSlova
binding energy; charge mobility; hopping transport
n3:klicoveSlovo
n4:charge%20mobility n4:binding%20energy n4:hopping%20transport
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[85C0088A59F6]
n3:nazevZdroje
Molecular Crystals and Liquid Crystals
n3:obor
n10:CD
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
7
n3:projekt
n8:KAN400720701 n8:IAA100100622
n3:rokUplatneniVysledku
n13:2010
n3:svazekPeriodika
521
n3:tvurceVysledku
Sworakowski, J. Nešpůrek, Stanislav Kochalska, Anna Kadashchuk, A. Fishchuk, I. I. Nožár, Juraj Kajzar, F.
n3:wos
000278163100004
n3:zamer
n18:AV0Z40500505
s:issn
1542-1406
s:numberOfPages
12