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Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F10%3A00341743%21RIV11-GA0-61389013
rdf:type
skos:Concept n14:Vysledek
dcterms:description
Using 1H and 13C 1D and 2D NMR spectra, PFG diffusion measurements and 13C relaxations supported by DFT calculations, the temperature-dependent behavior of (EO)m(PO)n(EO)m block copolymers (m/n = 31/14, 31/72, and 17/1) in D2O below and at the critical micellar temperature (CMT) was investigated. Changes in cooperative hydrophobic hydration and hydrogen bonds are found as primary pre-association process below CMT. Using 1H and 13C 1D and 2D NMR spectra, PFG diffusion measurements and 13C relaxations supported by DFT calculations, the temperature-dependent behavior of (EO)m(PO)n(EO)m block copolymers (m/n = 31/14, 31/72, and 17/1) in D2O below and at the critical micellar temperature (CMT) was investigated. Changes in cooperative hydrophobic hydration and hydrogen bonds are found as primary pre-association process below CMT.
dcterms:title
Cooperative preassociation stages of PEO-PPO-PEO triblock copolymers: NMR and theoretical study Cooperative preassociation stages of PEO-PPO-PEO triblock copolymers: NMR and theoretical study
skos:prefLabel
Cooperative preassociation stages of PEO-PPO-PEO triblock copolymers: NMR and theoretical study Cooperative preassociation stages of PEO-PPO-PEO triblock copolymers: NMR and theoretical study
skos:notation
RIV/61389013:_____/10:00341743!RIV11-GA0-61389013
n3:aktivita
n10:Z n10:P
n3:aktivity
P(GA203/09/1478), Z(AV0Z40500505)
n3:cisloPeriodika
9
n3:dodaniDat
n11:2011
n3:domaciTvurceVysledku
n8:1518755 n8:5079977
n3:druhVysledku
n18:J
n3:duvernostUdaju
n4:S
n3:entitaPredkladatele
n17:predkladatel
n3:idSjednocenehoVysledku
252149
n3:idVysledku
RIV/61389013:_____/10:00341743
n3:jazykVysledku
n16:eng
n3:klicovaSlova
pluronics; pre-association; hydrophobic hydration; NMR; DFT
n3:klicoveSlovo
n5:NMR n5:pluronics n5:hydrophobic%20hydration n5:DFT n5:pre-association
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[F7136AE1EF18]
n3:nazevZdroje
Journal of Physical Chemistry B
n3:obor
n7:CD
n3:pocetDomacichTvurcuVysledku
2
n3:pocetTvurcuVysledku
2
n3:projekt
n9:GA203%2F09%2F1478
n3:rokUplatneniVysledku
n11:2010
n3:svazekPeriodika
114
n3:tvurceVysledku
Kříž, Jaroslav Dybal, Jiří
n3:wos
000275047900008
n3:zamer
n12:AV0Z40500505
s:issn
1520-6106
s:numberOfPages
12