This HTML5 document contains 43 embedded RDF statements represented using HTML+Microdata notation.

The embedded RDF content will be recognized by any processor of HTML5 Microdata.

Namespace Prefixes

PrefixIRI
dctermshttp://purl.org/dc/terms/
n11http://linked.opendata.cz/resource/domain/vavai/projekt/
n7http://linked.opendata.cz/resource/domain/vavai/riv/tvurce/
n17http://linked.opendata.cz/ontology/domain/vavai/
n10http://linked.opendata.cz/resource/domain/vavai/zamer/
shttp://schema.org/
skoshttp://www.w3.org/2004/02/skos/core#
n3http://linked.opendata.cz/ontology/domain/vavai/riv/
n12http://linked.opendata.cz/resource/domain/vavai/vysledek/RIV%2F61389013%3A_____%2F09%3A00332179%21RIV10-AV0-61389013/
n2http://linked.opendata.cz/resource/domain/vavai/vysledek/
rdfhttp://www.w3.org/1999/02/22-rdf-syntax-ns#
n4http://linked.opendata.cz/ontology/domain/vavai/riv/klicoveSlovo/
n18http://linked.opendata.cz/ontology/domain/vavai/riv/duvernostUdaju/
xsdhhttp://www.w3.org/2001/XMLSchema#
n16http://linked.opendata.cz/ontology/domain/vavai/riv/aktivita/
n15http://linked.opendata.cz/ontology/domain/vavai/riv/jazykVysledku/
n13http://linked.opendata.cz/ontology/domain/vavai/riv/druhVysledku/
n6http://linked.opendata.cz/ontology/domain/vavai/riv/obor/
n8http://reference.data.gov.uk/id/gregorian-year/

Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F09%3A00332179%21RIV10-AV0-61389013
rdf:type
n17:Vysledek skos:Concept
dcterms:description
The extraction constant corresponding to the equilibrium K+(aq) + 1.Cs+(nb) equil. 1.K+(nb) + Cs+(aq) taking place in the two-phase water-nitrobenzene system was evaluated as -0.9 +/- 0.1. By using DFT calculations, the most probable structure of the 1.K+ complex species was derived, with the valinomycin part stabilized by strong bond interactions of K+ with six ester carbonyl oxygen atoms. The calculated stabilization energy of the considered cationic complex species 1.K+ is -376.1 kJ/mol, confirming the very high stability of the complex. The extraction constant corresponding to the equilibrium K+(aq) + 1.Cs+(nb) equil. 1.K+(nb) + Cs+(aq) taking place in the two-phase water-nitrobenzene system was evaluated as -0.9 +/- 0.1. By using DFT calculations, the most probable structure of the 1.K+ complex species was derived, with the valinomycin part stabilized by strong bond interactions of K+ with six ester carbonyl oxygen atoms. The calculated stabilization energy of the considered cationic complex species 1.K+ is -376.1 kJ/mol, confirming the very high stability of the complex.
dcterms:title
A combined extraction and DFT study on the complexation of K+ with valinomycin A combined extraction and DFT study on the complexation of K+ with valinomycin
skos:prefLabel
A combined extraction and DFT study on the complexation of K+ with valinomycin A combined extraction and DFT study on the complexation of K+ with valinomycin
skos:notation
RIV/61389013:_____/09:00332179!RIV10-AV0-61389013
n3:aktivita
n16:S n16:P n16:Z
n3:aktivity
P(1ET400500402), S, Z(AV0Z40500505), Z(MSM4977751303)
n3:cisloPeriodika
11
n3:dodaniDat
n8:2010
n3:domaciTvurceVysledku
n7:1518755
n3:druhVysledku
n13:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n12:predkladatel
n3:idSjednocenehoVysledku
301165
n3:idVysledku
RIV/61389013:_____/09:00332179
n3:jazykVysledku
n15:eng
n3:klicovaSlova
antibiotics; macrocycles; stability constant
n3:klicoveSlovo
n4:stability%20constant n4:antibiotics n4:macrocycles
n3:kodStatuVydavatele
AT - Rakouská republika
n3:kontrolniKodProRIV
[1736179FDB74]
n3:nazevZdroje
Monatshefte fur Chemie
n3:obor
n6:CD
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n11:1ET400500402
n3:rokUplatneniVysledku
n8:2009
n3:svazekPeriodika
140
n3:tvurceVysledku
Vaňura, P. Makrlík, E. Dybal, Jiří
n3:wos
000271503500004
n3:zamer
n10:MSM4977751303 n10:AV0Z40500505
s:issn
0026-9247
s:numberOfPages
4