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Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F09%3A00330992%21RIV10-AV0-61389013
rdf:type
skos:Concept n16:Vysledek
dcterms:description
From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1.Sr2+(nb) equil. 1.Zn2+(nb) + Sr2+(aq) in the two-phase water (aq) – nitrobenzene (nb) system (1: valinomycin) was evaluated as -0.2 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.Zn2+ complex species was predicted with the cation in the center of the coordination cavity formed by six ester carbonyls and binding energy of 359.5 kcal/mol. From extraction experiments and gamma-activity measurements, the exchange extraction constant corresponding to the equilibrium Zn2+(aq) + 1.Sr2+(nb) equil. 1.Zn2+(nb) + Sr2+(aq) in the two-phase water (aq) – nitrobenzene (nb) system (1: valinomycin) was evaluated as -0.2 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.Zn2+ complex species was predicted with the cation in the center of the coordination cavity formed by six ester carbonyls and binding energy of 359.5 kcal/mol.
dcterms:title
Experimental and DFT study on the complexation of Zn2+ with valinomycin Experimental and DFT study on the complexation of Zn2+ with valinomycin
skos:prefLabel
Experimental and DFT study on the complexation of Zn2+ with valinomycin Experimental and DFT study on the complexation of Zn2+ with valinomycin
skos:notation
RIV/61389013:_____/09:00330992!RIV10-AV0-61389013
n3:aktivita
n4:P n4:Z
n3:aktivity
P(1ET400500402), Z(AV0Z40500505)
n3:cisloPeriodika
8
n3:dodaniDat
n13:2010
n3:domaciTvurceVysledku
n14:1518755
n3:druhVysledku
n5:J
n3:duvernostUdaju
n15:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
314191
n3:idVysledku
RIV/61389013:_____/09:00330992
n3:jazykVysledku
n9:eng
n3:klicovaSlova
valinomycin; zinc; complexation
n3:klicoveSlovo
n7:complexation n7:zinc n7:valinomycin
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[2D3E5F8D4195]
n3:nazevZdroje
Zeitschrift für Kristallographie
n3:obor
n10:CD
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
3
n3:projekt
n11:1ET400500402
n3:rokUplatneniVysledku
n13:2009
n3:svazekPeriodika
223
n3:tvurceVysledku
Dybal, Jiří Vaňura, P. Makrlík, E.
n3:wos
000270615600005
n3:zamer
n17:AV0Z40500505
s:issn
0044-2968
s:numberOfPages
7