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Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F09%3A00330562%21RIV10-AV0-61389013
rdf:type
n12:Vysledek skos:Concept
dcterms:description
From extraction experiments and gamma-activity measurements, the extraction constant corresponding to the equilibrium H3O+(aq) + 1.Na+(nb) equil. 1.H3O+ (nb) + Na+ (aq) taking place in the two-phase water-nitrobenzene system (1: p-tert-butylcalix[4] arenetetrakis(N,N-dimethylacetamide)) was evaluated as -0.1 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.H3O+ cationic complex species was derived. From extraction experiments and gamma-activity measurements, the extraction constant corresponding to the equilibrium H3O+(aq) + 1.Na+(nb) equil. 1.H3O+ (nb) + Na+ (aq) taking place in the two-phase water-nitrobenzene system (1: p-tert-butylcalix[4] arenetetrakis(N,N-dimethylacetamide)) was evaluated as -0.1 +/- 0.1. By using quantum mechanical DFT calculations, the most probable structure of the 1.H3O+ cationic complex species was derived.
dcterms:title
Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide) Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide)
skos:prefLabel
Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide) Experimental evidence, stability, and the most probable structure of protonated p-tert-butylcalix[4]arenetetrakis (N,N-dimethylacetamide)
skos:notation
RIV/61389013:_____/09:00330562!RIV10-AV0-61389013
n4:aktivita
n11:Z n11:P
n4:aktivity
P(1ET400500402), Z(AV0Z40500505), Z(MSM4977751303), Z(MSM6046137307)
n4:cisloPeriodika
10
n4:dodaniDat
n14:2010
n4:domaciTvurceVysledku
n16:1518755
n4:druhVysledku
n13:J
n4:duvernostUdaju
n9:S
n4:entitaPredkladatele
n7:predkladatel
n4:idSjednocenehoVysledku
314224
n4:idVysledku
RIV/61389013:_____/09:00330562
n4:jazykVysledku
n15:eng
n4:klicovaSlova
calixarenes; macrocycles; protonation
n4:klicoveSlovo
n10:calixarenes n10:protonation n10:macrocycles
n4:kodStatuVydavatele
AT - Rakouská republika
n4:kontrolniKodProRIV
[1329768F38E0]
n4:nazevZdroje
Monatshefte fur Chemie
n4:obor
n18:CD
n4:pocetDomacichTvurcuVysledku
1
n4:pocetTvurcuVysledku
4
n4:projekt
n17:1ET400500402
n4:rokUplatneniVysledku
n14:2009
n4:svazekPeriodika
140
n4:tvurceVysledku
Makrlík, E. Budka, J. Vaňura, P. Dybal, Jiří
n4:wos
000270185100005
n4:zamer
n5:AV0Z40500505 n5:MSM4977751303 n5:MSM6046137307
s:issn
0026-9247
s:numberOfPages
4