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Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F09%3A00325489%21RIV09-AV0-61389013
rdf:type
skos:Concept n14:Vysledek
dcterms:description
ATR FTIR spectroscopy and quantum chemical calculations were used to investigate temperature dependent changes of structure and polymer–water interactions in a comparative study of poly(ethylene oxide), poly(propylene oxide) and a series of ethylene oxide–propylene oxide–ethylene oxide tri-block copolymers (Poloxamers, Pluronics) with different lengths of the blocks in aqueous media. It was found that both hydrophilic and hydrophobic interactions are significant for the temperature dependent phase behaviour. A model for the structural changes during the temperature transitions was specified. ATR FTIR spectroscopy and quantum chemical calculations were used to investigate temperature dependent changes of structure and polymer–water interactions in a comparative study of poly(ethylene oxide), poly(propylene oxide) and a series of ethylene oxide–propylene oxide–ethylene oxide tri-block copolymers (Poloxamers, Pluronics) with different lengths of the blocks in aqueous media. It was found that both hydrophilic and hydrophobic interactions are significant for the temperature dependent phase behaviour. A model for the structural changes during the temperature transitions was specified. ATR FTIR spektroskopie a kvantově chemické výpočty byly využity ke studiu teplotně závislých změn struktury a interakcí polymer-voda ve srovnávací studii polyetylenoxidu, polypropylenoxidu a série trojblokových kopolymerů etylenoxid-propylenoxid-etyleneoxid (Poloxamer, Pluronic) s různou délkou bloků ve vodním prostředí. Bylo zjištěno, že jak hydrofilní tak hydrofobní interakce jsou významné pro teplotně závislé fázové chování. Byl navržen model strukturních změn při teplotních přechodech.
dcterms:title
Studium interakcí a teplotních přechodů polyetylenoxidu, polypropylenoxidu a trojblokového kopolymeru etylenoxid-propylenoxid-etyleneoxid ve vodním prostředí pomocí ATR FTIR ATR FTIR investigation of interactions and temperature transitions of poly(ethylene oxide), poly(propylene oxide) and ethylene oxide-propylene oxide-ethylene oxide tri-block copolymers in water media ATR FTIR investigation of interactions and temperature transitions of poly(ethylene oxide), poly(propylene oxide) and ethylene oxide-propylene oxide-ethylene oxide tri-block copolymers in water media
skos:prefLabel
Studium interakcí a teplotních přechodů polyetylenoxidu, polypropylenoxidu a trojblokového kopolymeru etylenoxid-propylenoxid-etyleneoxid ve vodním prostředí pomocí ATR FTIR ATR FTIR investigation of interactions and temperature transitions of poly(ethylene oxide), poly(propylene oxide) and ethylene oxide-propylene oxide-ethylene oxide tri-block copolymers in water media ATR FTIR investigation of interactions and temperature transitions of poly(ethylene oxide), poly(propylene oxide) and ethylene oxide-propylene oxide-ethylene oxide tri-block copolymers in water media
skos:notation
RIV/61389013:_____/09:00325489!RIV09-AV0-61389013
n4:aktivita
n8:P n8:Z
n4:aktivity
P(1ET400500402), P(GA203/05/0425), Z(AV0Z40500505)
n4:cisloPeriodika
2
n4:dodaniDat
n10:2009
n4:domaciTvurceVysledku
n5:1926284 n5:8481954 n5:1518755
n4:druhVysledku
n9:J
n4:duvernostUdaju
n12:S
n4:entitaPredkladatele
n16:predkladatel
n4:idSjednocenehoVysledku
304353
n4:idVysledku
RIV/61389013:_____/09:00325489
n4:jazykVysledku
n17:eng
n4:klicovaSlova
structure; water-soluble polyethers; transition temperature
n4:klicoveSlovo
n11:structure n11:water-soluble%20polyethers n11:transition%20temperature
n4:kodStatuVydavatele
NL - Nizozemsko
n4:kontrolniKodProRIV
[75EE35D09EE1]
n4:nazevZdroje
Vibrational Spectroscopy
n4:obor
n15:CD
n4:pocetDomacichTvurcuVysledku
3
n4:pocetTvurcuVysledku
3
n4:projekt
n13:1ET400500402 n13:GA203%2F05%2F0425
n4:rokUplatneniVysledku
n10:2009
n4:svazekPeriodika
50
n4:tvurceVysledku
Dybal, Jiří Šturcová, Adriana Schmidt, Pavel
n4:wos
000267644100008
n4:zamer
n18:AV0Z40500505
s:issn
0924-2031
s:numberOfPages
8