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Statements

Subject Item
n2:RIV%2F61389013%3A_____%2F01%3A55010339%21RIV%2F2003%2FAV0%2FA55003%2FN
rdf:type
n14:Vysledek skos:Concept
dcterms:description
Molecular mechanism of the inhibition reaction of lactam peroxy radicals with phenoxy and diphenylaminyl radicals, yielding imide groups from peroxy radicals, was studied by ab initio quantum chemical methods. The reaction proceeds through a four-membered ring reaction center, breakage of the O-O bond of the lactam peroxy radical, with simultaneous transfer of hydrogen from the carbon atom to the departing oxygen. Molecular mechanism of the inhibition reaction of lactam peroxy radicals with phenoxy and diphenylaminyl radicals, yielding imide groups from peroxy radicals, was studied by ab initio quantum chemical methods. The reaction proceeds through a four-membered ring reaction center, breakage of the O-O bond of the lactam peroxy radical, with simultaneous transfer of hydrogen from the carbon atom to the departing oxygen.
dcterms:title
An ab initio quantum chemical study of reactions of hexano-6-lactam peroxy radicals with phenoxy or diphenyl radicals. An ab initio quantum chemical study of reactions of hexano-6-lactam peroxy radicals with phenoxy or diphenyl radicals.
skos:prefLabel
An ab initio quantum chemical study of reactions of hexano-6-lactam peroxy radicals with phenoxy or diphenyl radicals. An ab initio quantum chemical study of reactions of hexano-6-lactam peroxy radicals with phenoxy or diphenyl radicals.
skos:notation
RIV/61389013:_____/01:55010339!RIV/2003/AV0/A55003/N
n3:strany
569;577
n3:aktivita
n4:P n4:Z
n3:aktivity
P(IAA4050702), P(KSK2050602), Z(AV0Z4050913)
n3:cisloPeriodika
3
n3:dodaniDat
n6:2003
n3:domaciTvurceVysledku
n13:5117062
n3:druhVysledku
n5:J
n3:duvernostUdaju
n16:S
n3:entitaPredkladatele
n18:predkladatel
n3:idSjednocenehoVysledku
672974
n3:idVysledku
RIV/61389013:_____/01:55010339
n3:jazykVysledku
n11:eng
n3:klicovaSlova
ab initio calculations; lactams; reaction mechanism
n3:klicoveSlovo
n10:ab%20initio%20calculations n10:lactams n10:reaction%20mechanism
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[596FB2A73D71]
n3:nazevZdroje
Polymer Degradation and Stability
n3:obor
n17:CF
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
2
n3:pocetUcastnikuAkce
0
n3:pocetZahranicnichUcastnikuAkce
0
n3:projekt
n12:KSK2050602 n12:IAA4050702
n3:rokUplatneniVysledku
n6:2001
n3:svazekPeriodika
74
n3:tvurceVysledku
Lánská, Božena Burda, J.
n3:zamer
n15:AV0Z4050913
s:issn
0141-3910
s:numberOfPages
9