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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F14%3A00438737%21RIV15-GA0-61388980
rdf:type
skos:Concept n18:Vysledek
dcterms:description
Complete assignments of chemical shifts in the H-1 and C-13 NMR spectra for a contiguous series of [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) cations (where n = 0-6) are reported. The spectra revealed a straightforward linear correlation between delta(H-1) or delta(C-13) parameters of the cyclohexadienyl (Chd) and cyclopentadienyl (Cp) rings and the number of arene methyl substituents (n), which is consistent with an additive character of the interligand substituent effect and its transmission onto the second (Chd or Cp) ring via the Fe-II center. Complete assignments of chemical shifts in the H-1 and C-13 NMR spectra for a contiguous series of [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) cations (where n = 0-6) are reported. The spectra revealed a straightforward linear correlation between delta(H-1) or delta(C-13) parameters of the cyclohexadienyl (Chd) and cyclopentadienyl (Cp) rings and the number of arene methyl substituents (n), which is consistent with an additive character of the interligand substituent effect and its transmission onto the second (Chd or Cp) ring via the Fe-II center.
dcterms:title
Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations
skos:prefLabel
Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations Additivity of Interligand Substituent Effects for the Isoelectronic [(eta(5)-C6H7)Fe(eta(6)-MenC6H6-n)](+) and [(eta(5)-C5H5)Fe(eta(6)-MenC6H6-n)](+) Sandwich Cations
skos:notation
RIV/61388980:_____/14:00438737!RIV15-GA0-61388980
n3:aktivita
n13:P n13:I
n3:aktivity
I, P(GAP207/11/0705)
n3:cisloPeriodika
11
n3:dodaniDat
n5:2015
n3:domaciTvurceVysledku
n8:2449285 n8:6951082 n8:5101921
n3:druhVysledku
n11:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n10:predkladatel
n3:idSjednocenehoVysledku
1628
n3:idVysledku
RIV/61388980:_____/14:00438737
n3:jazykVysledku
n16:eng
n3:klicovaSlova
iron complexes; exchange; ligand
n3:klicoveSlovo
n12:ligand n12:iron%20complexes n12:exchange
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[85D0B3EEAB31]
n3:nazevZdroje
Organometallics
n3:obor
n4:CA
n3:pocetDomacichTvurcuVysledku
3
n3:pocetTvurcuVysledku
3
n3:projekt
n14:GAP207%2F11%2F0705
n3:rokUplatneniVysledku
n5:2014
n3:svazekPeriodika
33
n3:tvurceVysledku
Štíbr, Bohumil Turek, Jan Olejník, Roman
n3:wos
000337121700028
s:issn
0276-7333
s:numberOfPages
4
n17:doi
10.1021/om500165w