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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F12%3A00387954%21RIV13-AV0-61388980
rdf:type
skos:Concept n13:Vysledek
dcterms:description
The photosensitized oxidation of 2-chlorophenol (2-CP) in aqueous solution using immobilized meso-tetraphenylporphyrin (TPP) in polyurethane nanofabrics was studied. The influence of various parameters on the reaction efficiency was investigated, i.e., 2-CP concentration, oxygen content and pH of the reaction solution and the stability of immobilized photosensitizer at the multiple use. The resistance of the structure of the photosensitizer carrier toward the solutions of various pH was also studied. The participation of molecular singlet oxygen (O-1(2)) in the photooxidation was tested using NaN3 and imidazole quenchers of O-1(2). The kinetics of the process was described using Langmuir-Hinshelwood model. The photosensitized oxidation of 2-chlorophenol (2-CP) in aqueous solution using immobilized meso-tetraphenylporphyrin (TPP) in polyurethane nanofabrics was studied. The influence of various parameters on the reaction efficiency was investigated, i.e., 2-CP concentration, oxygen content and pH of the reaction solution and the stability of immobilized photosensitizer at the multiple use. The resistance of the structure of the photosensitizer carrier toward the solutions of various pH was also studied. The participation of molecular singlet oxygen (O-1(2)) in the photooxidation was tested using NaN3 and imidazole quenchers of O-1(2). The kinetics of the process was described using Langmuir-Hinshelwood model.
dcterms:title
2-Chlorophenol photooxidation using immobilized meso-tetraphenylporphyrin in polyurethane nanofabrics 2-Chlorophenol photooxidation using immobilized meso-tetraphenylporphyrin in polyurethane nanofabrics
skos:prefLabel
2-Chlorophenol photooxidation using immobilized meso-tetraphenylporphyrin in polyurethane nanofabrics 2-Chlorophenol photooxidation using immobilized meso-tetraphenylporphyrin in polyurethane nanofabrics
skos:notation
RIV/61388980:_____/12:00387954!RIV13-AV0-61388980
n13:predkladatel
n14:ico%3A61388980
n5:aktivita
n6:I
n5:aktivity
I
n5:cisloPeriodika
9
n5:dodaniDat
n17:2013
n5:domaciTvurceVysledku
n10:5799457
n5:druhVysledku
n9:J
n5:duvernostUdaju
n11:S
n5:entitaPredkladatele
n16:predkladatel
n5:idSjednocenehoVysledku
183320
n5:idVysledku
RIV/61388980:_____/12:00387954
n5:jazykVysledku
n18:eng
n5:klicovaSlova
SINGLET OXYGEN PRODUCTION; AQUEOUS-SOLUTIONS; SUBSTITUTED PHENOLS; CHLOROPHENOLS
n5:klicoveSlovo
n7:SUBSTITUTED%20PHENOLS n7:CHLOROPHENOLS n7:AQUEOUS-SOLUTIONS n7:SINGLET%20OXYGEN%20PRODUCTION
n5:kodStatuVydavatele
FR - Francouzská republika
n5:kontrolniKodProRIV
[56DB3B77BCB3]
n5:nazevZdroje
Photochemical & Photobiological Sciences
n5:obor
n8:CA
n5:pocetDomacichTvurcuVysledku
1
n5:pocetTvurcuVysledku
3
n5:rokUplatneniVysledku
n17:2012
n5:svazekPeriodika
11
n5:tvurceVysledku
Gmurek, M. Miller, J. S. Mosinger, Jiří
n5:wos
000307583800003
s:issn
1474-905X
s:numberOfPages
6
n12:doi
10.1039/c2pp25010a