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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F11%3A00364411%21RIV12-AV0-61388980
rdf:type
n6:Vysledek skos:Concept
dcterms:description
Metallaborane compounds containing two adjacent metal atoms, [(PMe(2)Ph)(4)MM'B(10)H(10)] (where MM' = Pt(2)., 1; PtPd, 7; Pd(2), 8), have been synthesized, and their propensity to sequester O(2), CO, and SO(2) and to then release them under pulsed and continuous irradiation are described. Only [(PMe(2)Ph)(4)Pt(2)B(10)H(10)], 1, undergoes reversible binding of O(2) to form [(PMe(2)Ph)(4)(O(2))Pt(2)B(10)H(10)] 3, but solutions of 1, 7, and 8 all quantitatively take up CO across their metal-metal vectors to form [(PMe(2)Ph)(4)(CO)Pt(2)B(10)H(10)] 4, [(PMe(2)Ph)(4)(CO)PtPdB(10)H(10)] 10, and [(PMe(2)Ph)(4)(CO)Pd(2)B(10)H(10)] 11, respectively. Crystallographically determined interatomic M-M distances and infrared CO stretching frequencies show that the CO molecule is bound progressively more weakly in the sequence {PtPt} > {PtPd} > {PdPd}. Metallaborane compounds containing two adjacent metal atoms, [(PMe(2)Ph)(4)MM'B(10)H(10)] (where MM' = Pt(2)., 1; PtPd, 7; Pd(2), 8), have been synthesized, and their propensity to sequester O(2), CO, and SO(2) and to then release them under pulsed and continuous irradiation are described. Only [(PMe(2)Ph)(4)Pt(2)B(10)H(10)], 1, undergoes reversible binding of O(2) to form [(PMe(2)Ph)(4)(O(2))Pt(2)B(10)H(10)] 3, but solutions of 1, 7, and 8 all quantitatively take up CO across their metal-metal vectors to form [(PMe(2)Ph)(4)(CO)Pt(2)B(10)H(10)] 4, [(PMe(2)Ph)(4)(CO)PtPdB(10)H(10)] 10, and [(PMe(2)Ph)(4)(CO)Pd(2)B(10)H(10)] 11, respectively. Crystallographically determined interatomic M-M distances and infrared CO stretching frequencies show that the CO molecule is bound progressively more weakly in the sequence {PtPt} > {PtPd} > {PdPd}.
dcterms:title
Reversible Capture of Small Molecules On Bimetallaborane Clusters: Synthesis, Structural Characterization, and Photophysical Aspects Reversible Capture of Small Molecules On Bimetallaborane Clusters: Synthesis, Structural Characterization, and Photophysical Aspects
skos:prefLabel
Reversible Capture of Small Molecules On Bimetallaborane Clusters: Synthesis, Structural Characterization, and Photophysical Aspects Reversible Capture of Small Molecules On Bimetallaborane Clusters: Synthesis, Structural Characterization, and Photophysical Aspects
skos:notation
RIV/61388980:_____/11:00364411!RIV12-AV0-61388980
n6:predkladatel
n15:ico%3A61388980
n3:aktivita
n4:Z n4:P
n3:aktivity
P(GAP207/11/1577), P(GAP208/10/1678), P(KAN400480701), Z(AV0Z40320502), Z(AV0Z40400503)
n3:cisloPeriodika
16
n3:dodaniDat
n7:2012
n3:domaciTvurceVysledku
Londesborough, Michael Geoffrey Stephen n18:3009459 Bould, Jonathan n18:3350037
n3:druhVysledku
n19:J
n3:duvernostUdaju
n20:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
226908
n3:idVysledku
RIV/61388980:_____/11:00364411
n3:jazykVysledku
n17:eng
n3:klicovaSlova
metallaborane reaction chemistry; metal-metal bonds; sulfur-dioxide; singlet oxygen; photochemical elimination
n3:klicoveSlovo
n12:sulfur-dioxide n12:singlet%20oxygen n12:metal-metal%20bonds n12:metallaborane%20reaction%20chemistry n12:photochemical%20elimination
n3:kodStatuVydavatele
US - Spojené státy americké
n3:kontrolniKodProRIV
[FDBF67E7F985]
n3:nazevZdroje
Inorganic Chemistry
n3:obor
n14:CA
n3:pocetDomacichTvurcuVysledku
4
n3:pocetTvurcuVysledku
10
n3:projekt
n5:KAN400480701 n5:GAP207%2F11%2F1577 n5:GAP208%2F10%2F1678
n3:rokUplatneniVysledku
n7:2011
n3:svazekPeriodika
50
n3:tvurceVysledku
Macias, R. Lang, Kamil Fuciman, M. Kubát, Pavel Bould, Jonathan Kennedy, J. D. Polívka, T. Baše, Tomáš Oro, L. A. Londesborough, Michael Geoffrey Stephen
n3:wos
000293493100022
n3:zamer
n9:AV0Z40320502 n9:AV0Z40400503
s:issn
0020-1669
s:numberOfPages
13
n8:doi
10.1021/ic200374k