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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F11%3A00358361%21RIV12-AV0-61388980
rdf:type
skos:Concept n6:Vysledek
dcterms:description
Reactions of (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh(cod) with Br-2 or I-2 give complexes [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10) RhX2](2) (X=Br (2a), I (2b)). Reaction of 2b with TIBF4 affords cation [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10)(2)Rh-2(mu-I)(3)](+) (3). Complex 2a reacts with Tl[Tl(eta-7,8-C2B9H11)] giving the bis(carborane) complex (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh (eta-7,8-C2B9H11) (4). Structures of 2a,b were determined by X-ray diffraction. Reactions of (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh(cod) with Br-2 or I-2 give complexes [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10) RhX2](2) (X=Br (2a), I (2b)). Reaction of 2b with TIBF4 affords cation [(eta-1-(BuNH)-Bu-t-1,7.9-C3B8H10)(2)Rh-2(mu-I)(3)](+) (3). Complex 2a reacts with Tl[Tl(eta-7,8-C2B9H11)] giving the bis(carborane) complex (eta-1-(BuNH)-Bu-t-1,7,9-C3B8H10)Rh (eta-7,8-C2B9H11) (4). Structures of 2a,b were determined by X-ray diffraction.
dcterms:title
The first (tricarbollide)rhodium halide complexes The first (tricarbollide)rhodium halide complexes
skos:prefLabel
The first (tricarbollide)rhodium halide complexes The first (tricarbollide)rhodium halide complexes
skos:notation
RIV/61388980:_____/11:00358361!RIV12-AV0-61388980
n6:predkladatel
n7:ico%3A61388980
n3:aktivita
n13:Z n13:P
n3:aktivity
P(LC523), Z(AV0Z40320502)
n3:cisloPeriodika
1
n3:dodaniDat
n12:2012
n3:domaciTvurceVysledku
n4:1509640
n3:druhVysledku
n17:J
n3:duvernostUdaju
n10:S
n3:entitaPredkladatele
n11:predkladatel
n3:idSjednocenehoVysledku
199865
n3:idVysledku
RIV/61388980:_____/11:00358361
n3:jazykVysledku
n20:eng
n3:klicovaSlova
boranes; metallacarboranes; rhodium; tricarbollide
n3:klicoveSlovo
n9:boranes n9:tricarbollide n9:rhodium n9:metallacarboranes
n3:kodStatuVydavatele
NL - Nizozemsko
n3:kontrolniKodProRIV
[38047163C426]
n3:nazevZdroje
Inorganic Chemistry Communications
n3:obor
n15:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:projekt
n5:LC523
n3:rokUplatneniVysledku
n12:2011
n3:svazekPeriodika
14
n3:tvurceVysledku
Loginov, D. A. Petrovskii, P. V. Starikova, Z. A. Holub, Josef Kudinov, A. R.
n3:wos
000287269000081
n3:zamer
n19:AV0Z40320502
s:issn
1387-7003
s:numberOfPages
3
n14:doi
10.1016/j.inoche.2010.11.024