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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F10%3A00355604%21RIV11-MSM-61388980
rdf:type
n7:Vysledek skos:Concept
dcterms:description
A ruthenium complex (Hoveyda–Grubbs second-generation) catalyzed cross-metathesis of allylcarboranes with perfluoroalkylpropenes under standard reaction conditions furnished perfluoroalkylated carboranes in good isolated yields (31–53%). The reaction proceeded with various carboranes and carborane sandwich complexes bearing the bridging allylthioether moiety. This method constitutes a simple and versatile procedure for the preparation of fluorophilic carboranes. A ruthenium complex (Hoveyda–Grubbs second-generation) catalyzed cross-metathesis of allylcarboranes with perfluoroalkylpropenes under standard reaction conditions furnished perfluoroalkylated carboranes in good isolated yields (31–53%). The reaction proceeded with various carboranes and carborane sandwich complexes bearing the bridging allylthioether moiety. This method constitutes a simple and versatile procedure for the preparation of fluorophilic carboranes.
dcterms:title
Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes
skos:prefLabel
Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes Synthesis of Perfluoroalkylated Carboranes by Cross-Metathesis of Allylcarboranes and Perfluoroalkylpropenes
skos:notation
RIV/61388980:_____/10:00355604!RIV11-MSM-61388980
n3:aktivita
n11:S n11:P n11:Z
n3:aktivity
P(LC06070), P(LC06077), P(LC523), S, Z(AV0Z40320502), Z(AV0Z40550506), Z(MSM0021620857)
n3:cisloPeriodika
6
n3:dodaniDat
n15:2011
n3:domaciTvurceVysledku
n12:4302834
n3:druhVysledku
n8:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n4:predkladatel
n3:idSjednocenehoVysledku
291544
n3:idVysledku
RIV/61388980:_____/10:00355604
n3:jazykVysledku
n13:eng
n3:klicovaSlova
metathesis; perfluoroalkylation; ruthenium; carboranes; metallacarboranes
n3:klicoveSlovo
n16:metathesis n16:metallacarboranes n16:ruthenium n16:carboranes n16:perfluoroalkylation
n3:kodStatuVydavatele
DE - Spolková republika Německo
n3:kontrolniKodProRIV
[EE02836D1CC5]
n3:nazevZdroje
Synlett
n3:obor
n6:CC
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
4
n3:projekt
n10:LC06077 n10:LC06070 n10:LC523
n3:rokUplatneniVysledku
n15:2010
n3:svazekPeriodika
-
n3:tvurceVysledku
Eignerová, Barbara Kotora, M. Dračínský, Martin Janoušek, Zbyněk
n3:wos
000275848800008
n3:zamer
n17:AV0Z40320502 n17:MSM0021620857 n17:AV0Z40550506
s:issn
0936-5214
s:numberOfPages
4