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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F10%3A00354532%21RIV11-MSM-61388980
rdf:type
n11:Vysledek skos:Concept
dcterms:description
Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4. Reaction of the tricarbollide anion [7,8,9-C3B8H11](-) (1a) with the naphthalene complex [CpRu(C10H8)](+) under visible light irradiation in CH2Cl2 gives the 12-vertex closo-rthenacarborane 1-Cp-1,2,3,5-RuC3B8H11 (2; 87% yield). This complex was also obtained by reaction of 1a with CpRu(cod) Cl (97%). Upon heating at 80 C in toluene 2 rearranges into isomer 1-Cp-1,2,4,10-RuC3B8H11 (3; 63%). Irradiation of 1a with [CpRu(C10H8)](+) in acetone gives the 11-vertex closo-1-Cp-1,2,3,4-RuC3B7H10 (4; 32%). The latter was also prepared by reaction of 1a with [CpRu(MeCN)(3)]+ (59%). Compound 2 slowly undergoes cage contraction in acetone giving 4.
dcterms:title
Cyclopentadienyl ruthenium comlexes with tricarbolide ligands Cyclopentadienyl ruthenium comlexes with tricarbolide ligands
skos:prefLabel
Cyclopentadienyl ruthenium comlexes with tricarbolide ligands Cyclopentadienyl ruthenium comlexes with tricarbolide ligands
skos:notation
RIV/61388980:_____/10:00354532!RIV11-MSM-61388980
n3:aktivita
n13:Z n13:P
n3:aktivity
P(LC523), Z(AV0Z40320502)
n3:cisloPeriodika
11
n3:dodaniDat
n6:2011
n3:domaciTvurceVysledku
n10:1509640
n3:druhVysledku
n4:J
n3:duvernostUdaju
n9:S
n3:entitaPredkladatele
n8:predkladatel
n3:idSjednocenehoVysledku
252607
n3:idVysledku
RIV/61388980:_____/10:00354532
n3:jazykVysledku
n15:eng
n3:klicovaSlova
boron; metallacarborane; ruthenium; tricarbollide
n3:klicoveSlovo
n7:ruthenium n7:tricarbollide n7:boron n7:metallacarborane
n3:kodStatuVydavatele
CZ - Česká republika
n3:kontrolniKodProRIV
[4DB054A24A4E]
n3:nazevZdroje
Collection of Czechoslovak Chemical Communications
n3:obor
n17:CA
n3:pocetDomacichTvurcuVysledku
1
n3:pocetTvurcuVysledku
5
n3:projekt
n18:LC523
n3:rokUplatneniVysledku
n6:2010
n3:svazekPeriodika
75
n3:tvurceVysledku
Holub, Josef Trifonova, E. A. Kudinov, A. R. Glukhov, I. V. Perekalin, D. S.
n3:wos
000284230500006
n3:zamer
n16:AV0Z40320502
s:issn
0010-0765
s:numberOfPages
10