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Statements

Subject Item
n2:RIV%2F61388980%3A_____%2F10%3A00349146%21RIV11-MSM-61388980
rdf:type
n13:Vysledek skos:Concept
dcterms:description
The interaction between flat silver surfaces and carboranethiol derivatives, and its relevance regarding the molecular protection of silver against corrosion by hydrogen sulphide, are reported here. A comparison of the protective qualities of four carboranethiols (1-HS-1,2-C2B10H11, 1,2-(HS)(2)-1,2-C2B10H10, 9,12-(HS)(2)-1,2-C2B10H10, and 1,12-(HS)(2)-1,2-C2B10H10) with several organic thiols (1-butanethiol, 1-octanethiol, 1-dodecanethiol, benzene-1,2-dithiol, benzenethiol, and sodium 2-mercaptoethanesulphonate) is provided. All these derivatives are categorized according to their capacity to inhibit the interaction of silver with H2S in the presence of water molecules in the gas phase. We found that significantly better molecular protection for silver surfaces is afforded by the carboranethiol derivatives, and, of these, 9,12-(HS)(2)-1,2-C2B10H10 proved to be particularly effective. The interaction between flat silver surfaces and carboranethiol derivatives, and its relevance regarding the molecular protection of silver against corrosion by hydrogen sulphide, are reported here. A comparison of the protective qualities of four carboranethiols (1-HS-1,2-C2B10H11, 1,2-(HS)(2)-1,2-C2B10H10, 9,12-(HS)(2)-1,2-C2B10H10, and 1,12-(HS)(2)-1,2-C2B10H10) with several organic thiols (1-butanethiol, 1-octanethiol, 1-dodecanethiol, benzene-1,2-dithiol, benzenethiol, and sodium 2-mercaptoethanesulphonate) is provided. All these derivatives are categorized according to their capacity to inhibit the interaction of silver with H2S in the presence of water molecules in the gas phase. We found that significantly better molecular protection for silver surfaces is afforded by the carboranethiol derivatives, and, of these, 9,12-(HS)(2)-1,2-C2B10H10 proved to be particularly effective.
dcterms:title
Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces
skos:prefLabel
Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces Carborane-thiol-silver interactions. A comparative study of the molecular protection of silver surfaces
skos:notation
RIV/61388980:_____/10:00349146!RIV11-MSM-61388980
n3:aktivita
n17:P n17:Z
n3:aktivity
P(IAA400320901), P(KAN100400702), P(KAN400480701), P(LC06041), P(LC523), Z(AV0Z10480505), Z(AV0Z40320502), Z(AV0Z40400503)
n3:cisloPeriodika
16-17
n3:dodaniDat
n5:2011
n3:domaciTvurceVysledku
n6:8071845 n6:1797271 n6:3009459 Londesborough, Michael Geoffrey Stephen Bould, Jonathan n6:3350037
n3:druhVysledku
n14:J
n3:duvernostUdaju
n18:S
n3:entitaPredkladatele
n16:predkladatel
n3:idSjednocenehoVysledku
249620
n3:idVysledku
RIV/61388980:_____/10:00349146
n3:jazykVysledku
n10:eng
n3:klicovaSlova
silver; self assembly; corrosion; nanostructure
n3:klicoveSlovo
n9:corrosion n9:self%20assembly n9:silver n9:nanostructure
n3:kodStatuVydavatele
CH - Švýcarská konfederace
n3:kontrolniKodProRIV
[0D6612897119]
n3:nazevZdroje
Surface and Coatings Technology
n3:obor
n7:CA
n3:pocetDomacichTvurcuVysledku
6
n3:pocetTvurcuVysledku
8
n3:projekt
n8:KAN100400702 n8:KAN400480701 n8:LC523 n8:IAA400320901 n8:LC06041
n3:rokUplatneniVysledku
n5:2010
n3:svazekPeriodika
204
n3:tvurceVysledku
Bastl, Zdeněk Havránek, Vladimír Baše, Tomáš Londesborough, Michael Geoffrey Stephen Lang, Kamil Macháček, Jan Bould, Jonathan Plešek, Jaromír
n3:wos
000277736100018
n3:zamer
n4:AV0Z40400503 n4:AV0Z10480505 n4:AV0Z40320502
s:issn
0257-8972
s:numberOfPages
8